用作分析试剂，用于钢铁中磷、碳的测定。还用作线路板蚀刻添加剂。
| 英文名 | diazanium,tetrachlorocopper(2-) |
|---|---|
| 英文别名 |
Cuprate(2-),tetrachloro-,ammonium (1:2)
diazanium tetrachlorocopper(2-) Diammonium tetrachlorocuprate Cuprate(2-),tetrachloro-,diammonium EINECS 239-690-5 Ammonium cupric chloride diammonium tetrachlorocuprate(2-) |
| 分子式 | Cl4CuH8N2 |
|---|---|
| 分子量 | 241.43500 |
| 精确质量 | 238.87400 |
| PSA | 6.48000 |
| 稳定性 | 110~120ºC 成无水物，温度再高则分解。 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:2 3.氢键受体数量:1 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积2 7.重原子数量:7 8.表面电荷:0 9.复杂度:19.1 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:3 |
| 更多 | 一、物性数据 1. 性状：蓝色或蓝色结晶或颗粒 2. 密度(g/mL,25/4℃）：1.993 3. 相对蒸汽密度（g/mL,空气=1）： 4. 熔点（ºC）：110 5. 沸点（ºC,常压）： 6. 沸点（ºC,5.2kPa）： 7. 折射率： 8. 闪点（ºC）： 9. 比旋光度（º）： 10. 自燃点或引燃温度（ºC）： 11. 蒸气压（kPa,25ºC）： 12. 饱和蒸气压（kPa,60ºC）： 13. 燃烧热（KJ/mol）： 14. 临界温度（ºC）： 15. 临界压力（KPa）： 16. 油水（辛醇/水）分配系数的对数值： 17. 爆炸上限（%,V/V）： 18. 爆炸下限（%,V/V）： 19. 溶解性：易溶于水、溶于氨水、乙醇。 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes respiratory tract irritation. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Storage: Store in a cool, dry place. Keep container closed when not in use. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits CAS# 15610-76-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: light blue Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 110 deg C (decomposes) Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: 110 deg C Solubility in water: Soluble in water. Specific Gravity/Density: Not available. Molecular Formula: CuCl3N2H12O2.2H2O Molecular Weight: 278.028 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Chlorine, carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 15610-76-1 unlisted. LD50/LC50: Not available. Carcinogenicity: Ammonium Copper (II) Chloride Dihydrate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 21/22 Harmful in contact with skin and if swallowed. Safety Phrases: S 20 When using do not eat or drink. S 37 Wear suitable gloves. WGK (Water Danger/Protection) CAS# 15610-76-1: No information available. Canada CAS# 15610-76-1 is listed on Canada's NDSL List. CAS# 15610-76-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 15610-76-1 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |