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环己甲腈

环己甲腈名称

[ CAS 号 ]:
766-05-2

[ 中文名 ]:
环己甲腈

[ 英文名 ]:
Cyclohexanecarbonitrile

[中文别名 ]:

环己基甲腈

[英文别名 ]:

tetrahydrobenzonitrile
Hexahydrobenzonitril [German]
cyclohexylcarbonitrile
Cyclohexanecarboxylic acid nitrile
EINECS 212-157-4
hexahydrobenzonitrile
Cyclohexanecarbonitrile
cyclohexane carbonitrile
Cyclohexyl cyanide
Cyclohexanecarboxylic acid nitrite

环己甲腈物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
199.8±9.0 °C at 760 mmHg

[ 熔点 ]:
11 °C(lit.)

[ 分子式 ]:
C₇H₁₁N

[ 分子量 ]:
109.169

[ 闪点 ]:
68.8±6.5 °C

[ 精确质量 ]:
109.089149

[ PSA ]:
23.79000

[ LogP ]:
1.61

[ 蒸汽压 ]:
0.3±0.4 mmHg at 25°C

[ 折射率 ]:
1.452

[ 储存条件 ]:
2-8°C

环己甲腈MSDS

环己甲腈毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GU7280000

CHEMICAL NAME :: Cyclohexanecarbonitrile

CAS REGISTRY NUMBER :: 766-05-2

LAST UPDATED :: 199709

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C7-H11-N

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 80 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

REFERENCE :: ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

REFERENCE :: ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 200 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

REFERENCE :: ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969

环己甲腈安全信息

[ 符号 ]:

GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311

[ 警示性声明 ]:
P280-P301 + P310-P312

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R23/24/25;R36/37/38

[ 安全声明 (欧洲) ]:
S36/37-S45-S36/37/39-S26-S23

[ 危险品运输编码 ]:
UN 3276 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
GU7280000

环己甲腈合成路线

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环己甲腈文献

Rhodium-catalyzed regioselective arylation of phenylazoles and related compounds with arylboron reagents via C-H bond cleavage. Miyamura S, et al.

J. Organomet. Chem. 693(14) , 2438-42, (2008)

C-metalated nitriles: electrophile-dependent alkylations and acylations.

J. Org. Chem. 71(4) , 1430-5, (2006)

Sequential carbonyl addition-conjugate addition of Grignard reagents to 3-oxocyclohex-1-ene-1-carbonitrile generates C-magnesiated nitriles whose alkylation stereoselectivities intimately depend on th...

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