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1,4-二碘丁烷

1,4-二碘丁烷名称

[ CAS 号 ]:
628-21-7

[ 中文名 ]:
1,4-二碘代丁烷

[ 英文名 ]:
1,4-Diiodobutane

[中文别名 ]:

[英文别名 ]:

BUTANE,1,4-DIIODO
Tetramethylene iodide
EINECS 211-032-1
1,4-di-iodobutane
Butane, 1,4-diiodo-
Tetramethylene diiodide
1,4-Diiodobutane
1,4-Diodobutane
1,4-diidobutane
Butane,4-diiodo

1,4-二碘丁烷物理化学性质

[ 密度 ]:
2.3±0.1 g/cm3

[ 沸点 ]:
246.1±8.0 °C at 760 mmHg

[ 熔点 ]:
6 °C(lit.)

[ 分子式 ]:
C₄H₈I₂

[ 分子量 ]:
309.915

[ 闪点 ]:
116.7±13.9 °C

[ 精确质量 ]:
309.871521

[ LogP ]:
3.44

[ 外观性状 ]:
透明淡棕色液体,强烈的气味

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.621

[ 储存条件 ]:
室温，密封

[ 水溶解性 ]:
insoluble

1,4-二碘丁烷MSDS

1,4-二碘丁烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EJ9200000

CHEMICAL NAME :: Butane, 1,4-diiodo-

CAS REGISTRY NUMBER :: 628-21-7

BEILSTEIN REFERENCE NO. :: 1098276

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C4-H8-I2

MOLECULAR WEIGHT :: 309.92

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 10 umol/plate

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 141,11,1984

1,4-二碘丁烷安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
2810

[ WGK德国 ]:
3

[ RTECS号 ]:
EJ9200000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
29033080

1,4-二碘丁烷合成路线

1,4-二碘丁烷上下游产品

1,4-二碘丁烷上游产品

1,4-二碘丁烷下游产品

1,4-二碘丁烷制备

1.制法：

于装有搅拌器、回流冷凝器、温度计的反应瓶中，加入32.5g五氧化二磷，85%的正磷酸68mL，搅拌下冷至室温。加入碘化钾166g(1.0mol),22.5（0.25mol）新蒸馏的1,4-丁二醇(2)(bp228～230℃或133～135℃/2.4kPa)。搅拌下于100～120℃反应4h。冷至室温，加入75mL水和130mL乙醚。分出乙醚层，加入25mL（10%）的硫代硫酸钠溶液脱色，用冷的饱和食盐水洗涤，无水流行美干燥。蒸出乙醚后，减压分馏，收集110℃/800Pa的馏分，得1,4-二碘丁烷(1) ^①65g,收率84%。注：①也可以使用THF代替1,4-丁二醇。

1,4-二碘丁烷海关

[ 海关编码 ]: 2903399090

[ 中文概述 ]:
2903399090. 其他无环烃的氟化、溴化或碘化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

1,4-二碘丁烷文献

Gas chromatographic determination of busulfan in plasma with electron-capture detection.

J. Chromatogr. A. 277 , 374-80, (1983)

Biliary excretion of a glutathione conjugate of busulfan and 1,4-diiodobutane in the rat.

Drug Metab. Dispos. 16(1) , 85-92, (1988)

gamma-Glutamyl-beta-(S-tetrahydrothiophenium)alanyl-glycine, the glutathione-sulfonium conjugate of busulfan and 1,4-diiodobutane, was identified in the bile of rats following intravenous administrati...

Glutathione S-transferases catalyzed conjugation of 1,4-disubstituted butanes with glutathione in vitro.

Biochem. Biophys. Res. Commun. 128(1) , 360-7, (1985)

Rat liver glutathione S-transferases catalyzed the conjugation of 1,4-diiodobutane with glutathione in vitro. The reaction followed saturation kinetics and was dependent on the concentration of the en...

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