(S,S,S)-DiazaPhos-PPE

(S,S,S)-DiazaPhos-PPE用途

在Rh催化的不对称加氢甲酰化反应中，重氮磷烷配体显示出极好的选择性和转化率。 Diazaphospholane ligands display excellent levels of selectivity and conversion in Rh-catalyzed asymmetric hydroformylation reactions.

(S,S,S)-DiazaPhos-PPE名称

[ CAS 号 ]:
615538-63-1

[ 英文名 ]:
(S,S,S)-DiazaPhos-PPE

[英文别名 ]:

(S,S,S)-Diazaphos-ppe

(S,S,S)-DiazaPhos-PPE物理化学性质

[ 分子式 ]:
C₄₆H₃₉N₄O₄P

[ 分子量 ]:
742.8

[ 精确质量 ]:
742.270874

[ LogP ]:
6.80

(S,S,S)-DiazaPhos-PPE安全信息

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

(S,S,S)-DiazaPhos-PPE文献

Highly active, regioselective, and enantioselective hydroformylation with Rh catalysts ligated by Bis-3,4-diazaphospholanes.

J. Am. Chem. Soc. 127 , 5040, (2005)

Azines made by the reaction of hydrazine with ortho-formylbenzoic acid react with 1,2-diphosphinobenzene and either succinyl chloride or phthaloyl chloride in ca. 30% yield to give rac-bis-3,4-diazaph...

Highly regio- and enantioselective asymmetric hydroformylation of olefins mediated by 2,5-disubstituted phospholane ligands.

Angew. Chem. Int. Ed. Engl. 44 , 5834, (2005)

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