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(S,S,S)-DiazaPhos-PPE

更新时间:2024-01-11 16:58:02

(S,S,S)-DiazaPhos-PPE结构式
(S,S,S)-DiazaPhos-PPE结构式
品牌特惠专场
常用名 (S,S,S)-DiazaPhos-PPE 英文名 (S,S,S)-DiazaPhos-PPE
CAS号 615538-63-1 分子量 742.8
密度 N/A 沸点 N/A
分子式 C46H39N4O4P 熔点 N/A
MSDS 美版 闪点 N/A

 (S,S,S)-DiazaPhos-PPE用途


在Rh催化的不对称加氢甲酰化反应中,重氮磷烷配体显示出极好的选择性和转化率。 Diazaphospholane ligands display excellent levels of selectivity and conversion in Rh-catalyzed asymmetric hydroformylation reactions.

 (S,S,S)-DiazaPhos-PPE名称

英文名 (S,S,S)-DiazaPhos-PPE
英文别名 更多

 (S,S,S)-DiazaPhos-PPE物理化学性质

分子式 C46H39N4O4P
分子量 742.8
精确质量 742.270874
LogP 6.80

 (S,S,S)-DiazaPhos-PPE安全信息

危险品运输编码 NONH for all modes of transport
WGK德国 3

 (S,S,S)-DiazaPhos-PPE文献2

更多文献
Highly active, regioselective, and enantioselective hydroformylation with Rh catalysts ligated by Bis-3,4-diazaphospholanes.

J. Am. Chem. Soc. 127 , 5040, (2005)

Azines made by the reaction of hydrazine with ortho-formylbenzoic acid react with 1,2-diphosphinobenzene and either succinyl chloride or phthaloyl chloride in ca. 30% yield to give rac-bis-3,4-diazaph...

Highly regio- and enantioselective asymmetric hydroformylation of olefins mediated by 2,5-disubstituted phospholane ligands.

Angew. Chem. Int. Ed. Engl. 44 , 5834, (2005)

 (S,S,S)-DiazaPhos-PPE英文别名

Benzamide, 2,2'-[(1S,3S)-2,3,5,10-tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-[(1S)-1-phenylethyl]-
2,2'-[(1S,3S)-2,3,5,10-Tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-(1S)-1-phenylethyl]benzamide
(S,S,S)-Diazaphos-ppe
2,2'-[(1S,3S)-5,10-Dioxo-2-phenyl-2,3,5,10-tetrahydro-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis{N-[(1S)-1-phenylethyl]benzamide}
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