![]() (S,S,S)-DiazaPhos-PPE结构式
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常用名 | (S,S,S)-DiazaPhos-PPE | 英文名 | (S,S,S)-DiazaPhos-PPE |
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CAS号 | 615538-63-1 | 分子量 | 742.8 | |
密度 | N/A | 沸点 | N/A | |
分子式 | C46H39N4O4P | 熔点 | N/A | |
MSDS | 美版 | 闪点 | N/A |
(S,S,S)-DiazaPhos-PPE用途在Rh催化的不对称加氢甲酰化反应中,重氮磷烷配体显示出极好的选择性和转化率。 Diazaphospholane ligands display excellent levels of selectivity and conversion in Rh-catalyzed asymmetric hydroformylation reactions. |
英文名 | (S,S,S)-DiazaPhos-PPE |
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英文别名 | 更多 |
分子式 | C46H39N4O4P |
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分子量 | 742.8 |
精确质量 | 742.270874 |
LogP | 6.80 |
危险品运输编码 | NONH for all modes of transport |
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WGK德国 | 3 |
Highly active, regioselective, and enantioselective hydroformylation with Rh catalysts ligated by Bis-3,4-diazaphospholanes.
J. Am. Chem. Soc. 127 , 5040, (2005) Azines made by the reaction of hydrazine with ortho-formylbenzoic acid react with 1,2-diphosphinobenzene and either succinyl chloride or phthaloyl chloride in ca. 30% yield to give rac-bis-3,4-diazaph... |
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Highly regio- and enantioselective asymmetric hydroformylation of olefins mediated by 2,5-disubstituted phospholane ligands.
Angew. Chem. Int. Ed. Engl. 44 , 5834, (2005)
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Benzamide, 2,2'-[(1S,3S)-2,3,5,10-tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-[(1S)-1-phenylethyl]- |
2,2'-[(1S,3S)-2,3,5,10-Tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-(1S)-1-phenylethyl]benzamide |
(S,S,S)-Diazaphos-ppe |
2,2'-[(1S,3S)-5,10-Dioxo-2-phenyl-2,3,5,10-tetrahydro-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis{N-[(1S)-1-phenylethyl]benzamide} |