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醋酸镍(四水)

醋酸镍(四水)用途

【用途一】
主要用于镀镍、金属着色、制镍催化剂，用作织物媒染剂等
【用途二】
化学试剂。工业上用作织物媒染剂，也用于电镀。
【用途三】
试剂，织物媒染剂。

醋酸镍(四水)名称

[ CAS 号 ]:
6018-89-9

[ 中文名 ]:
醋酸镍(四水)

[ 英文名 ]:
nickel acetate tetrahydrate

[中文别名 ]:

[英文别名 ]:

Acetic acid, nickel(2+) salt, hydrate (2:1:2)
nickel(II) acetate tetrahydrate
MFCD00066973
nickel acetate tetrahydrate
Nickel(2+) acetate hydrate (1:2:4)
EINECS 206-761-7
nickel(2+),diacetate,tetrahydrate

醋酸镍(四水)物理化学性质

[ 密度 ]:
1.798 g/mL at 25 °C(lit.)

[ 沸点 ]:
117.1ºC at 760 mmHg

[ 熔点 ]:
°Cd ec.)

[ 分子式 ]:
C₄H₁₄NiO₈

[ 分子量 ]:
248.843

[ 闪点 ]:
40ºC

[ 精确质量 ]:
248.004211

[ PSA ]:
89.52000

[ 外观性状 ]:
绿色结晶粉末

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (吸湿)

[ 稳定性 ]:
Stable.

[ 水溶解性 ]:
182 g/L (20 ºC)

醋酸镍(四水)MSDS

醋酸镍(四水)毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QR6126000

CHEMICAL NAME :: Nickel acetate tetrahydrate

CAS REGISTRY NUMBER :: 6018-89-9

LAST UPDATED :: 199801

DATA ITEMS CITED :: 14

MOLECULAR FORMULA :: C4-H6-O4.Ni.4H2-O

MOLECULAR WEIGHT :: 248.89

WISWESSER LINE NOTATION :: OV1 2 &-NI- &QH 4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 350 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 410 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 45700 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: DNA damage

MUTATION DATA

TYPE OF TEST :: Cytogenetic analysis

TEST SYSTEM :: Rodent - mouse Mammary gland

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 68,337,1979 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,257,1990 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

醋酸镍(四水)安全信息

[ 符号 ]:

GHS07, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302 + H332-H317-H334-H341-H350i-H360D-H372-H410

[ 警示性声明 ]:
P201-P261-P273-P280-P284-P304 + P340 + P312

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R22;R40;R43

[ 安全声明 (欧洲) ]:
S53-S36/37-S45-S24-S22

[ 危险品运输编码 ]:
UN 3077 9 / PGIII

[ WGK德国 ]:
3

[ RTECS号 ]:
QR6126000

[ 包装等级 ]:
III

醋酸镍(四水)合成路线

醋酸镍(四水)上下游产品

醋酸镍(四水)上游产品

醋酸镍(四水)下游产品

醋酸镍(四水)制备

1.奖碱式碳酸镍溶于过量的稀乙酸溶液中，过滤，蒸发，冷却析出结晶，抽干后将结晶于70℃干燥，即得成品。

2.硫酸镍与醋酸钡在水溶液中进行复分解，过滤出硫酸钡，滤液经浓缩析出结晶，即得四水合物。

3.将硫酸镍溶液和碳酸钠溶液反应制得碳酸镍，沉淀经洗涤数次后，用乙酸溶液溶解碳酸镍而制得乙酸镍，经浓缩、干燥即得成品。

醋酸镍(四水)文献

Layer by Layer Ex-Situ Deposited Cobalt-Manganese Oxide as Composite Electrode Material for Electrochemical Capacitor.

PLoS ONE 10 , e0129780, (2015)

The composite metal oxide electrode films were fabricated using ex situ electrodeposition method with further heating treatment at 300°C. The obtained composite metal oxide film had a spherical struct...

Control of I-V hysteresis in CH3NH3PbI3 perovskite solar cell.

J. Phys. Chem. Lett. 6 , 4633-9, (2015)

Mismatch of current (I)-voltage (V) curves with respect to the scan direction, so-called I-V hysteresis, raises critical issue in MAPbI3 (MA = CH3NH3) perovskite solar cell. Although ferroelectric and...

Sodium thiosulfate-assisted synthesis of NiS₂ nanostructure by using nickel(II)-Salen precursor: optical and magnetic properties.

Dalton Trans. 43(44) , 16745-53, (2014)

A NiS2 nanostructure with a protective layer of Ni(2+) and SO4(2-) ions around it has been successfully synthesized using the Ni(II)-Salen (Salen = N,N'-bis(salicylidene)ethylenediamine) complex via a...

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