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对伞花烃二氯化钌二聚体

对伞花烃二氯化钌二聚体名称

[ CAS 号 ]:
52462-29-0

[ 中文名 ]:
二氯(p-甲基异丙苯)钌(II) 二聚体

[ 英文名 ]:
Dichloro(p-cymene)ruthenium(II) dimer

[中文别名 ]:

[英文别名 ]:

DICHLORO(P-CYMENE)RUTHENIUM(II) DIMER
MFCD00064793
Dichloro(p-cymene)ruthenium dimer
dichlororuthenium,1-methyl-4-propan-2-ylbenzene
(p-Cymene)ruthenium(II) chloride dimer Benzene
1-methyl-4-(1-methylethyl)-,ruthenium complex
1Y1&R D1 &&RuCl2 complex 2:2
p-Cymeneruthenium(II) Dichloride Dimer
Dichloro(p-cymene)ruthenium(II)dimer
Di-μ-chloro-bis[chloro(p-cymene)ruthenium(II)]

对伞花烃二氯化钌二聚体物理化学性质

[ 沸点 ]:
173.9ºC at 760mmHg

[ 熔点 ]:
247.0-250.0 °C (dec.)(lit.)

[ 分子式 ]:
C₂₀H₂₈Cl₄Ru₂

[ 分子量 ]:
612.388

[ 闪点 ]:
47.2ºC

[ 精确质量 ]:
611.903259

[ LogP ]:
8.99480

[ 外观性状 ]:
红色-橙色至红色-棕色晶体或粉末

[ 储存条件 ]:
2~8°C，密封，避光

[ 水溶解性 ]:
不溶

对伞花烃二氯化钌二聚体MSDS

详细MSDS(安全技术说明书)

对伞花烃二氯化钌二聚体安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H319-H412

[ 警示性声明 ]:
P273-P305 + P351 + P338

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R36;R52/53

[ 安全声明 (欧洲) ]:
26-61

[ 危险品运输编码 ]:
UN 2811 6.1/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
TA2312000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29310095

对伞花烃二氯化钌二聚体海关

[ 海关编码 ]: 29310095

对伞花烃二氯化钌二聚体文献

Cyclometallation of arylimines and nitrogen-containing heterocycles via room-temperature C-H bond activation with arene ruthenium(II) acetate complexes.

Dalton Trans. 36th ed., 41 , 10934-10937, (2012)

The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprot...

Ru-catalysed C-H arylation of indoles and pyrroles with boronic acids: scope and mechanistic studies.

Chemistry 21(14) , 5380-6, (2015)

The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range...

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