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碘代异丁烷

碘代异丁烷用途

【用途一】
用作有机溶剂，也用于有机合成
【用途二】
用作溶剂、分析试剂、有机合成原料。

碘代异丁烷名称

[ CAS 号 ]:
513-38-2

[ 中文名 ]:
碘代异丁烷

[ 英文名 ]:
1-Iodo-2-methylpropane

[中文别名 ]:

[英文别名 ]:

MFCD00001084
Isobutyl Iodide
1-Iodo-2-methylpropane
Propane, 1-iodo-2-methyl-
EINECS 208-160-5
1-Iodo-2-methylpropane,stabilized

碘代异丁烷物理化学性质

[ 密度 ]:
1.6±0.1 g/cm3

[ 沸点 ]:
120.0±8.0 °C at 760 mmHg

[ 熔点 ]:
-93 °C

[ 分子式 ]:
C₄H₉I

[ 分子量 ]:
184.019

[ 闪点 ]:
12.8±0.0 °C

[ 精确质量 ]:
183.974884

[ LogP ]:
2.91

[ 外观性状 ]:
透明至琥珀色液体

[ 蒸汽密度 ]:
6 (vs air)

[ 蒸汽压 ]:
18.6±0.2 mmHg at 25°C

[ 折射率 ]:
1.501

[ 储存条件 ]:
库房通风低温干燥避光,与氧化剂分开存放

[ 水溶解性 ]:
insoluble

碘代异丁烷MSDS

详细MSDS(安全技术说明书)

碘代异丁烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TZ4250000

CHEMICAL NAME :: Propane, 1-iodo-2-methyl-

CAS REGISTRY NUMBER :: 513-38-2

BEILSTEIN REFERENCE NO. :: 1730927

LAST UPDATED :: 199709

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C4-H9-I

MOLECULAR WEIGHT :: 184.03

WISWESSER LINE NOTATION :: I1Y1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 6700 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,756,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1241 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,756,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 594 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,756,1969

碘代异丁烷安全信息

[ 符号 ]:

GHS02, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H315-H319-H331-H335

[ 警示性声明 ]:
P210-P261-P305 + P351 + P338-P311

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable;Xn:Harmful;

[ 风险声明 (欧洲) ]:
R11;R20;R36/37/38

[ 安全声明 (欧洲) ]:
S16-S26-S36-S9-S33

[ 危险品运输编码 ]:
UN 2391 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
TZ4250000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
29033080

碘代异丁烷合成路线

详细合成路线

碘代异丁烷上下游产品

碘代异丁烷上游产品

碘代异丁烷下游产品

碘代异丁烷制备

由异丁醇与三碘化磷反应而得。先将赤磷与异丁醇混合，在水浴上加热，慢慢加入碘，加完后继续反应4h，经蒸馏得粗品。粗品经洗涤、干燥、过滤，再经分馏，收集119~122℃馏分，即为成品。

碘代异丁烷海关

[ 海关编码 ]: 2903399090

[ 中文概述 ]:
2903399090. 其他无环烃的氟化、溴化或碘化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

碘代异丁烷文献

Vibrational analysis of alkyl iodides: 1-iodo-2-methylpropane and 1-iodo-3-methylbutane.

J. Mol. Struct. 49(2) , 287-292, (1978)

更多文献