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2-氟乙基氯甲酸

2-氟乙基氯甲酸名称

[ CAS 号 ]:
462-27-1

[ 中文名 ]:
2-氟乙基氯甲酸

[ 英文名 ]:
2-fluoroethyl chloroformate

[中文别名 ]:

2-氟氯乙酸甲酯

[英文别名 ]:

2-Fluoroethyl chloroformate
Chloroformic acid 2-fluoroethyl ester
carbonochloridic acid,2-fluoroethyl ester(9ci)
Chlorokohlensaeure-(2-fluor-aethylester)
Formic acid,chloro-,2-fluoroethyl ester
1-Chlorcarbonyloxy-2-fluor-aethan
MFCD01726287
chlorocarbonic acid-(2-fluoro-ethyl ester)
Chlorameisensaeure-(2-flour-aethylester)
2-fluoroethyl chloridocarbonate

2-氟乙基氯甲酸物理化学性质

[ 密度 ]:
1.286g/cm3

[ 沸点 ]:
115.5ºC at 760mmHg

[ 分子式 ]:
C₃H₄ClFO₂

[ 分子量 ]:
126.51400

[ 闪点 ]:
51.8ºC

[ 精确质量 ]:
125.98800

[ PSA ]:
26.30000

[ LogP ]:
1.33130

[ 蒸汽压 ]:
19mmHg at 25°C

[ 折射率 ]:
n20/D 1.4(lit.)

[ 储存条件 ]:
2-8°C

2-氟乙基氯甲酸MSDS

2-氟乙基氯甲酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: LQ6300000

CHEMICAL NAME :: Formic acid, chloro-, 2-fluoroethyl ester

CAS REGISTRY NUMBER :: 462-27-1

BEILSTEIN REFERENCE NO. :: 1746655

LAST UPDATED :: 199709

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C3-H4-Cl-F-O2

MOLECULAR WEIGHT :: 126.52

WISWESSER LINE NOTATION :: GVO2F

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 200 mg/kg/10M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: No.9-4-1-9,1943

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 100 mg/kg/10M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: No.9-4-1-9,1943

2-氟乙基氯甲酸安全信息

[ 符号 ]:

GHS02, GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H314-H331

[ 警示性声明 ]:
P210-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T: Toxic;

[ 风险声明 (欧洲) ]:
23-34

[ 安全声明 (欧洲) ]:
S26;S27;S45;S36/S37/S39

[ 危险品运输编码 ]:
UN 2742 6.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
LQ6300000

[ 海关编码 ]:
2915900090

2-氟乙基氯甲酸合成路线

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2-氟乙基氯甲酸海关

[ 海关编码 ]: 2915900090

[ 中文概述 ]:
2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

2-氟乙基氯甲酸文献

Notes-Synthesis and Investigation of Organic Fluorine Compounds. XXII. The Preparation of Newer 2-Fluoroethylurethan Derivatives. Olah G, et al.

J. Org. Chem. 22(8) , 979-980, (1957)

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