3-(4-甲氧基苯基)环氧乙烷-2-甲酸甲酯

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
297.7±40.0 °C at 760 mmHg

[ 熔点 ]:
69-71ºC(lit.)

[ 分子式 ]:
C₁₁H₁₂O₄

[ 分子量 ]:
208.211

[ 闪点 ]:
129.2±27.4 °C

[ 精确质量 ]:
208.073563

[ PSA ]:
48.06000

[ LogP ]:
1.27

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.534

详细MSDS(安全技术说明书)

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
36/37/38

[ 安全声明 (欧洲) ]:
26-37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

详细合成路线

3-(4-甲氧基苯基)环氧乙烷-2-甲酸甲酯上游产品

3-(4-甲氧基苯基)环氧乙烷-2-甲酸甲酯下游产品

J. Ind. Microbiol. Biotechnol. 31(11) , 525-30, (2004)

Lipase production and cell growth of Serratia marcescens ECU1010 were optimized in shake flasks, with lipase production being enhanced 9.5-fold (4,780 U/l) compared with the initial activity (500 U/l)...

J. Org. Chem. 67(13) , 4599-601, (2002)

A practical synthesis of methyl (2R,3S)-3-(4-methoxyphenyl)glycidate (-)-2, a key intermediate for diltiazem (1), was developed. Treatment of methyl (E)-4-methoxycinnamate 3 with chiral dioxirane, gen...

J. Org. Chem. 68(3) , 974-9, (2003)

An efficient synthesis of methyl (2R,3S)-3-(4-methoxyphenyl)glycidate (-)-2, a key intermediate for diltiazem (1), has been developed on the basis of the highly enantioselective Mukaiyama aldol reacti...

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