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N6-异戊烯基腺嘌呤

N6-异戊烯基腺嘌呤用途

6-(γ,γ-Dimethylallylamino)purine 是一种植物生长调节剂。

N6-异戊烯基腺嘌呤名称

[ CAS 号 ]:
2365-40-4

[ 中文名 ]:
烯腺嘌呤

[ 英文名 ]:
6-(γ,γ-Dimethylallylamino)purine

[中文别名 ]:

[英文别名 ]:

6-(y,y-Dimethylallylamino)purine
6-isopentenyladenine
MFCD00132998
N-(3-Methyl-2-buten-1-yl)-7H-purin-6-amine
N-(3-Methylbut-2-en-1-yl)-1H-purin-6-amin
iPeAde
6-[(3-methylbut-2-en-1-yl)amino]-9H-purine
N-(3-methylbut-2-enyl)-7H-purin-6-amine
6-[(3-Methyl-2-butenyl)amino]purine
N(6)-dimethylallyladenine

N6-异戊烯基腺嘌呤生物活性

[ 描述 ]:

6-(γ,γ-Dimethylallylamino)purine 是一种植物生长调节剂。

[ 相关类别 ]:

信号通路 >> 其他 >> 其他

研究领域 >> 其他

[体外研究]

衍生紫外光谱数据显示,植物生长物质6-(γ,γ-二甲基烯丙基氨基)嘌呤(N6-(δ-异戊烯基)腺嘌呤,i6Ade)和吲哚乙酸(IAA)可与酵母醇脱氢酶(ADH)结合,影响辅酶-酶结合。在固定的乙醇浓度(27.8和111.1 mM)和不同的NAD +浓度(0.033-2 mM),以及固定水平的辅酶(0.67和2 mM)和不同浓度的乙醇(1.4-111.1 mM)时, i6Ade和IAA显着抑制乙醇氧化速率。 ADH反应的动力学受两个抑制常数(Ki和Ki')的影响,这两个抑制常数分别对应于复合物EI和ESI的解离常数。对于i6Ade,Ki = 0.52±0.06mM,Ki'= 0.74±0.07mM,对于IAA,Ki = 0.88±0.03mM,Ki'= 0.99±0.02mM [1]。

[参考文献]

[1]. Zikmanis P, et al. Indolylacetic acid and N6-(delta 2-isopentenyl) adenine affect NADH binding to yeast alcohol dehydrogenase and inhibit in vitro the enzymatic oxidation of ethanol. Biofactors. 1990 Oct;2(4):237-40.

[相关活性小分子]

N6-异戊烯基腺嘌呤物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
477.1±30.0 °C at 760 mmHg

[ 分子式 ]:
C₁₀H₁₃N₅

[ 分子量 ]:
203.244

[ 闪点 ]:
242.4±24.6 °C

[ 精确质量 ]:
203.117096

[ PSA ]:
66.49000

[ LogP ]:
2.31

[ 外观性状 ]:
白色至灰白色粉末

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 折射率 ]:
1.683

[ 储存条件 ]:
-20°C

N6-异戊烯基腺嘌呤安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 危险品运输编码 ]:
NONH for all modes of transport

[ 海关编码 ]:
2934993000

N6-异戊烯基腺嘌呤合成路线

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N6-异戊烯基腺嘌呤海关

[ 海关编码 ]: 2933990090

[ 中文概述 ]:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

N6-异戊烯基腺嘌呤文献

Synthesis, characterization and biological activity of ring-substituted 6-benzylamino-9-tetrahydropyran-2-yl and 9-tetrahydrofuran-2-ylpurine derivatives

Bioorg. Med. Chem. 17 , 1938-47, (2009)

Synthesis of 9-tetrahydropyran-2-yl and 9-tetrahydrofuran-2-yl benzylaminopurines, their stability, cytokinin activity, perception by cytokinin receptors, degradation by cytokinin oxidase/dehydrogenas...

Thidiazuron influences the endogenous levels of cytokinins and IAA during the flowering of isolated shoots of Dendrobium.

J. Plant Physiol. 163(11) , 1126-34, (2006)

This study reports the effects of thidiazuron (TDZ) on the endogenous levels of indoleacetic acid (IAA), zeatin, zeatin riboside ([9R]Z), isopentenyladenine and isopentenyladenosine ([9R]iP) as well a...

Functional identification of OsHk6 as a homotypic cytokinin receptor in rice with preferential affinity for iP.

Plant Cell Physiol. 53(7) , 1334-43, (2012)

Cytokinins are involved in key developmental processes in rice (Oryza sativa), including the regulation of cell proliferation and grain yield. However, the in vivo action of histidine kinases (OsHks),...

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