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草达灭标准溶液

草达灭标准溶液用途

Molinate is a biochemical.

草达灭标准溶液名称

[ CAS 号 ]:
2212-67-1

[ 中文名 ]:
禾草敌

[ 英文名 ]:
molinate

[中文别名 ]:

[英文别名 ]:

UNII:68N5G08DJQ
Molmate
Jalan
EINECS 218-661-0
S-ethyl hexahydro-1H-azepine-1-carbothioate
Sakkimol
S-Ethyl 1-azepanecarbothioate
S-Ethyl azepane-1-carbothioate
S-ethyl perhydroazepine-1-carbothioate
S-ethylhexahydro-1H-azepine-1-carbothioate

草达灭标准溶液物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
279.0±23.0 °C at 760 mmHg

[ 分子式 ]:
C₉H₁₇NOS

[ 分子量 ]:
187.302

[ 闪点 ]:
122.6±22.6 °C

[ 精确质量 ]:
187.103088

[ PSA ]:
45.61000

[ LogP ]:
3.21

[ 外观性状 ]:
透明液体带有芳香气味

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.512

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

[ 水溶解性 ]:
0.08 g/100 mL

草达灭标准溶液MSDS

详细MSDS(安全技术说明书)

草达灭标准溶液毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CM2625000

CHEMICAL NAME :: 1H-Azepine-1-carbothioic acid, hexahydro-, S-ethyl ester

CAS REGISTRY NUMBER :: 2212-67-1

BEILSTEIN REFERENCE NO. :: 1239196

LAST UPDATED :: 199701

DATA ITEMS CITED :: 22

MOLECULAR FORMULA :: C9-H17-N-O-S

MOLECULAR WEIGHT :: 187.33

WISWESSER LINE NOTATION :: T7NTJ AVS2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 369 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2100 mg/m3/1H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1167 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 657 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - body temperature decrease

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 530 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Sense Organs and Special Senses (Eye) - changes in extra-ocular muscles Behavioral - somnolence (general depressed activity)

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 545 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - body temperature decrease

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: >200 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 3536 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 720 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3952 mg/kg/43W-I

TOXIC EFFECTS :: Endocrine - other changes Blood - normocytic anemia Nutritional and Gross Metabolic - body temperature decrease

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7818 mg/kg/17W-I

TOXIC EFFECTS :: Nutritional and Gross Metabolic - body temperature decrease Related to Chronic Data - death

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 113 mg/m3/30D-I

TOXIC EFFECTS :: Liver - liver function tests impaired Kidney, Ureter, Bladder - other changes in urine composition Blood - other changes

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4500 ug/m3/17W-I

TOXIC EFFECTS :: Kidney, Ureter, Bladder - other changes in urine composition

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 4500 ug/m3/17W-I

TOXIC EFFECTS :: Liver - liver function tests impaired Blood - other changes

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 324 mg/kg

SEX/DURATION :: male 90 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females) Reproductive - Effects on Newborn - viability index (e.g., # alive at day 4 per # born alive)

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 1620 mg/kg

SEX/DURATION :: male 90 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females) Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 640 ug/m3/6H

SEX/DURATION :: male 20 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 600 ug/m3/6H

SEX/DURATION :: male 20 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females)

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 350 mg/kg

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 242,279,1990 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

草达灭标准溶液安全信息

[ 符号 ]:

GHS07, GHS08, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302 + H332-H317-H351-H361-H373-H410

[ 警示性声明 ]:
P201-P261-P273-P280-P304 + P340 + P312-P308 + P313

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T,N,Xn

[ 风险声明 (欧洲) ]:
R20/22

[ 安全声明 (欧洲) ]:
S36/37-S46-S60-S61

[ 危险品运输编码 ]:
2902

[ RTECS号 ]:
CM2625000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
2933990017

草达灭标准溶液上下游产品

草达灭标准溶液上游产品

草达灭标准溶液下游产品

草达灭标准溶液制备

有光气法和氧硫化碳法。1.光气法将气与六甲撑亚胺反应生成六甲撑甲酰氯，进而在过量碱存在下与乙硫醇进行巯基化反应而得。亦可将光气先与乙硫醇反应生成S-乙基硫代氯甲酸酯，再与六甲撑亚胺反应而得。2.氧硫化碳法氧硫化碳在碱作用下与六甲撑亚胺反应，生成N，N-六甲撑硫化氨基甲酸钠，再与硫酸二乙酯或其他乙基化剂反应而得。氯甲酸友谊赶乙酯的制备在冷却条件下，于20～30℃将光气通入到乙硫醇和催化剂混合液中，然后反应混合物在没有外部冷却的情况下（保持干冰冷凝器）继续搅拌几小时，反应结束后用空气于20～30℃将过量光气驱除，反应混合物用4.5%盐酸和水洗涤，硫酸镁干燥，过滤，滤液真空回流除去挥发性杂质，回流冷凝中冷却水维持在氯甲酸硫赶乙酯能冷凝而硫醇不冷凝的温度，被蒸馏物温度保持恒定10min，停止回流。
六次甲基亚胺的制备在氢气和己内酰胺混合物露点以上温度形成蒸气混合物，并将该蒸气混合物通过240～270℃的加氢催化剂（预先需用脂肪族或脂环族烃C5～C6处理），配比为氢：己内酰胺=（10～100）：1 （mol)，压力5×10⁵～10×10⁵Pa，己内酰胺转化率为80%～100%，以转化的己内酰胺计，产率为97%～98%。
实例：将11.0标准m³/h氢和0.8kg/h己内酰胺加入到蒸发器中，蒸气混合物温度维持在240℃，即比生成的蒸气混合物露点高40℃，该混合物通入含3.5L Cu-Zn催化剂（Cu 40%、Zn 8%/硅藻土）的反应器（通入上述蒸气混合物前，将1.3kg环戊烷蒸气先通过反应器）。加氢过程于240℃、10×10⁵Pa下进行，己内酰胺转化率100%，六次甲基亚胺产率为98%。
禾草敌的合成将含14g (0.35mol)氢氧化钠的200mL水溶液与31.7g (0.32mol)六次甲基亚胺的100mL正戊烷混合后，在冷却下，将37.4g (0.30mol)氯甲酸硫赶乙酯加入到剧烈搅拌的混合物中，反应混合物的温度维持在15～20℃，加料完毕后，继续搅拌5min。静置分离，有机相用稀盐酸（5mL浓盐酸用水稀释至55mL）和水洗涤，无水硫酸镁干燥、过滤，并在蒸气浴上浓缩，残留液减压蒸馏，得禾草敌51.9g，产率92.3%。

草达灭标准溶液海关

[ 海关编码 ]: 2933990017

[ 中文概述 ]:
2933990017 唑草酯,四环唑,恶草酸等〔包括喹禾糠酯,哒草特,咯草隆,禾草敌,唑草胺,敌草快,氯草敏〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2933990017 6,7-dihydrodipyrido[1,2-a:2',1'-c]pyrazine-5,8-diium bromide。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

草达灭标准溶液文献

Shiga-like toxin B subunit of Escherichia coli as scaffold for high-avidity display of anti-immunocomplex peptides.

Anal. Chem. 86(11) , 5541-6, (2014)

Small compounds cannot bind simultaneously to two antibodies, and thus, their immunodetection is limited to competitive formats in which the analyte is indirectly quantitated by measuring the unoccupi...

Field dissipation and environmental hazard assessment of clomazone, molinate, and thiobencarb in Australian rice culture.

J. Agric. Food Chem. 54(19) , 7213-20, (2006)

The fates of clomazone [2-(2-chlorophenyl)methyl-4,4-dimethyl-3-isoxazolidinone], molinate (S-ethyl hexahydro-1-H-azepine-1-carbothioate), and thiobencarb {S-[(4-chlorophenyl)methyl]diethylcarbamothio...

Photocatalytic degradation of molinate in aqueous solutions.

Environ. Sci. Pollut. Res. Int. 21(21) , 12294-304, (2014)

In this study, the degradation of molinate through heterogeneous photocatalysis, using two different types of the semiconductor TiO2 as photocatalyst, as well as through homogeneous treatment, applyin...

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