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三亚苯

三亚苯用途

苊烯是有机合成原料，用于电绝缘材料和离子交换树脂、染料等。市售商品纯度为95%时，熔点88-91℃，熔点下的相对密度0.899。

三亚苯名称

[ CAS 号 ]:
217-59-4

[ 中文名 ]:
9,10-苯并菲

[ 英文名 ]:
Triphenylene

[中文别名 ]:

[英文别名 ]:

1,2:3,4-Dibenznaphthalene
isochrysene
6-Phenyl-5,6-dihydro-dibenz[1,2]azaborinin
10-phenyl-9,10-azaboraphenanthrene
9,10-azabora-phenanthrene
6-phenyl-5,6-dihydro-dibenzo[1,2]azaborinine
EINECS 205-922-9
MFCD00001108
10-Phenyl-10,9-borazaro-phenanthren
6-phenyl-5,6-dihydro-dibenz[1,2]azaborinine

三亚苯物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
425.0±0.0 °C at 760 mmHg

[ 熔点 ]:
195-198 °C(lit.)

[ 分子式 ]:
C₁₈H₁₂

[ 分子量 ]:
228.288

[ 闪点 ]:
209.1±13.7 °C

[ 精确质量 ]:
228.093903

[ LogP ]:
5.91

[ 外观性状 ]:
略米色

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.771

[ 储存条件 ]:
2-8°C

三亚苯MSDS

三亚苯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: YK2925000

CHEMICAL NAME :: Triphenylene

CAS REGISTRY NUMBER :: 217-59-4

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C18-H12

MOLECULAR WEIGHT :: 228.30

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in mammalian somatic cells

TEST SYSTEM :: Human Lymphocyte

DOSE/DURATION :: 20 umol/L

REFERENCE :: DTESD7 52 Vanderbilt Ave., New York, NY 10017) V.1-15, 1977-87. Discontinued 52 Vanderbilt Ave., New York, NY 10017) V.1- 1977- Volume(issue)/page/year: 10,277,1982 *** REVIEWS *** IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 32,447,1983 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 32,447,1983 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - T1252 No. of Facilities: 11 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 32 (estimated)

三亚苯安全信息

[ 符号 ]:

GHS05, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H318-H410

[ 警示性声明 ]:
P280-P305 + P351 + P338 + P310

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
R41

[ 安全声明 (欧洲) ]:
S22-S24/25-S61-S60-S39-S26

[ 危险品运输编码 ]:
UN 3077 9/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
YK2925000

[ 包装等级 ]:
II; III

[ 危险类别 ]:
4.1

三亚苯合成路线

三亚苯上下游产品

三亚苯上游产品

三亚苯下游产品

三亚苯制备

由苊经气相催化脱氢而得：将工业苊投入熔融釜，用间接蒸汽加热使全部熔化。用压缩空气将液苊压入螺旋气化混合器，用蒸汽加热气化，直接蒸汽与苊蒸气混合进入过热炉，过热至450±20℃，进入脱氢反应器，经催化脱氢反应，然后冷凝、干燥而得粗苊烯。用乙醇溶解粗苊烯，除去炭化物和机械杂质，冷却、结晶、干燥而得成品。所用催化剂为氧化锌（85%）、氧化钙（5%）、硫酸钾（5%）、铬酸钾（3%）、氢氧化钾（2%）。

三亚苯文献

QSPR modeling of octanol/water partition coefficient for vitamins by optimal descriptors calculated with SMILES.

Eur. J. Med. Chem. 43 , 714-40, (2008)

Simplified molecular input line entry system (SMILES) has been utilized in constructing quantitative structure-property relationships (QSPR) for octanol/water partition coefficient of vitamins and org...

UV photodissociation of ethylamine cation: a combined experimental and theoretical investigation.

J. Phys. Chem. A 114(51) , 13296-302, (2010)

Direct current (DC) slice imaging of state-selected ions is combined with high-level ab initio calculations to give insight into reaction pathways, dynamics, and energetics for ethylamine cation photo...

Triphenylene based copper ensemble for the detection of cyanide ions.

Dalton Trans. 41(37) , 11413-8, (2012)

The binding behavior of triphenylene based copper ensemble prepared in situ has been investigated toward various anions (F(-), Cl(-), Br(-), I(-), CH(3)COO(-), H(2)PO(4)(-), NO(3)(-), OH(-), ClO(4)(-)...

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三亚苯