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硝酸异丙酯

硝酸异丙酯用途

【用途一】
用作医药中间体
【用途二】
主要用作汽车燃料添加剂，喷气式飞机辅助推进剂。也用于医药中间体、溶剂。

硝酸异丙酯名称

[ CAS 号 ]:
1712-64-7

[ 中文名 ]:
硝酸异丙酯

[ 英文名 ]:
Isopropyl nitrate

[中文别名 ]:

硝酸異丙酯

[英文别名 ]:

Nitric acid, 1-methylethyl ester
propan-2-yl nitrate
Nitric acid isopropyl
2-nitrooxypropane
2-Propanol nitrate
(CH3)2CHONO2
Isopropyl nitrate
isopriopyl nitrate
1-methylethyl nitrate
Propan-2-ol nitrate

硝酸异丙酯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
99.6±8.0 °C at 760 mmHg

[ 分子式 ]:
C₃H₇NO₃

[ 分子量 ]:
105.093

[ 闪点 ]:
12.8±0.0 °C

[ 精确质量 ]:
105.042595

[ PSA ]:
55.05000

[ LogP ]:
1.43

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
43.7±0.2 mmHg at 25°C

[ 折射率 ]:
1.400

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放

[ 稳定性 ]:
Stability Highly flammable. Incompatible with strong reducing agents, strong acids, finely powdered metals, tin chloride, boron trifluoride.

硝酸异丙酯MSDS

硝酸异丙酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QU8930000

CHEMICAL NAME :: Nitric acid, isopropyl ester

CAS REGISTRY NUMBER :: 1712-64-7

BEILSTEIN REFERENCE NO. :: 1701405

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C3-H7-N-O3

MOLECULAR WEIGHT :: 105.11

WISWESSER LINE NOTATION :: WNOY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 29 gm/m3/2H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 33,110,1970

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 65 gm/m3/2H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,78,1982 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 5 mg/m3 JAN 1993 OEL-SWEDEN:TWA 10 ppm (45 mg/m3);STEL 15 ppm (70 mg/m3) JAN 1993

硝酸异丙酯安全信息

[ 符号 ]:

GHS02

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225

[ 警示性声明 ]:
P210

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
O:Oxidizingagent;F:Flammable;Xn:Harmful;

[ 风险声明 (欧洲) ]:
R5;R8;R11;R20

[ 安全声明 (欧洲) ]:
S16-S17-S33-S7/9

[ 危险品运输编码 ]:
UN 1222 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
QU8930000

[ 包装等级 ]:
II

[ 危险类别 ]:
3.1

[ 海关编码 ]:
2920909090

硝酸异丙酯合成路线

硝酸异丙酯上下游产品

硝酸异丙酯上游产品

硝酸异丙酯下游产品

硝酸异丙酯制备

异丙醇与硝酸在尿素存在下直接酯化。经分离、水洗、中和、干燥、精馏等过程得成品硝酸异丙酯。

硝酸异丙酯海关

[ 海关编码 ]: 2920909090

[ 中文概述 ]:
2920909090 其他无机酸酯（不包括卤化氢的酯）（包括其盐及它们的卤化，磺化，硝化和亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2920909090 esters of other inorganic acids of non-metals (excluding esters of hydrogen halides) and their salts; their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

硝酸异丙酯文献

Vibrational analysis of isopropyl nitrate and isobutyl nitrate.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 58(12) , 2571-80, (2002)

Raman and infrared spectra of isopropyl nitrate and isobutyl nitrate are reported. These spectra are used in combination with computational studies employing density functional theory at the B3-LYP/6-...

Biological monitoring of isopropyl nitrate.

Toxicol. Lett. 47(2) , 205-11, (1989)

Four healthy men were exposed to an isopropyl nitrate (IPN) concentration of 45.8 mg/m3 for 60 min. The IPN in the expired air, blood and urine of volunteers was analysed by gas chromatography. The lo...

Poppers-associated retinal toxicity.

N. Engl. J. Med. 363(16) , 1583-5, (2010)

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