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邻甲氧基苯甲醛

邻甲氧基苯甲醛用途

2-甲氧基苯甲醛(邻茴香醛),从肉桂精油(CEO)中分离得到,具有抗菌和抗真菌活性[1]。

邻甲氧基苯甲醛名称

[ CAS 号 ]:
135-02-4

[ 中文名 ]:
2-甲氧基苯甲醛

[ 英文名 ]:
o-Anisaldehyde

[中文别名 ]:

[英文别名 ]:

Benzaldehyde, 2-methoxy-
Salicylaldehyde Methyl Ether
o-Anisaldehyde
MFCD00003308
EINECS 205-171-7
2-Methoxybenzolcarbaldehyd
2-methoxybenzaldehyde
o-Anisaldehyde,Salicylaldehyde methyl ether

邻甲氧基苯甲醛生物活性

[ 描述 ]:

2-甲氧基苯甲醛(邻茴香醛),从肉桂精油(CEO)中分离得到,具有抗菌和抗真菌活性[1]。

[ 相关类别 ]:

研究领域 >> 感染

信号通路 >> 抗感染 >> 真菌

信号通路 >> 抗感染 >> 细菌

[参考文献]

[1]. Zhaoxiang Huang, et al. Synergistic effects of cinnamaldehyde and cinnamic acid in cinnamon essential oil against S. pullorum. Industrial Crops and Products, 2021-02-03.

[2]. Sheikh Shreaz, et al. Interesting anticandidal effects of anisic aldehydes on growth and proton-pumping-ATPase-targeted activity. Microb Pathog. 2011 Oct;51(4):277-84.

邻甲氧基苯甲醛物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
243.5±0.0 °C at 760 mmHg

[ 熔点 ]:
34-40 °C(lit.)

[ 分子式 ]:
C₈H₈O₂

[ 分子量 ]:
136.148

[ 闪点 ]:
117.8±0.0 °C

[ 精确质量 ]:
136.052429

[ PSA ]:
26.30000

[ LogP ]:
1.72

[ 外观性状 ]:
淡黄色至淡棕色

[ 蒸汽压 ]:
0.0±0.4 mmHg at 25°C

[ 折射率 ]:
1.547

[ 储存条件 ]:
库房通风低温干燥

[ 水溶解性 ]:
insoluble

邻甲氧基苯甲醛MSDS

邻甲氧基苯甲醛毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BZ2610000

CHEMICAL NAME :: o-Anisaldehyde

CAS REGISTRY NUMBER :: 135-02-4

BEILSTEIN REFERENCE NO. :: 0606301

LAST UPDATED :: 199710

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C8-H8-O2

MOLECULAR WEIGHT :: 136.16

WISWESSER LINE NOTATION :: VHR BO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2400 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity) Gastrointestinal - changes in structure or function of salivary glands

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Human Lymphocyte

DOSE/DURATION :: 125 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 206,17,1988

邻甲氧基苯甲醛安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
BZ2610000

[ 包装等级 ]:
I; II; III

[ 海关编码 ]:
29124900

邻甲氧基苯甲醛合成路线

邻甲氧基苯甲醛上下游产品

邻甲氧基苯甲醛上游产品

邻甲氧基苯甲醛下游产品

邻甲氧基苯甲醛制备

由水杨醛经与硫酸二甲酯甲基化反应而制得。将3kg氢氧化钠配成30%水溶液，在搅拌下加入含12.2kg水杨醛和80L水的溶液中，加热至沸。将12.9kg硫酸二甲酯慢慢加入，使反应液保持回流约3h加完，继续回流2-3h，冷却油层，用5%氢氧化钠溶液洗涤，再用水洗至pH为8，加无水碳酸钾干燥。滤除干燥剂后减压蒸馏，收集120℃（2.0kPa）馏分，即为邻甲氧基苯甲醛。甲基化反应也可在溶剂甲苯中进行，收率60%。

邻甲氧基苯甲醛海关

[ 海关编码 ]: 2912499000

[ 中文概述 ]:
2912499000. 其他醛醚、醛酚及含其他含氧基的醛. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 四聚甲醛报明外观

[ Summary ]:
2912499000. other aldehyde-ethers, aldehyde-phenols and aldehydes with other oxygen function. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

邻甲氧基苯甲醛文献

3D-QSAR and molecular docking studies of benzaldehyde thiosemicarbazone, benzaldehyde, benzoic acid, and their derivatives as phenoloxidase inhibitors.

Bioorg. Med. Chem. 15 , 2006-15, (2007)

Phenoloxidase (PO), also known as tyrosinase, is a key enzyme in insect development, responsible for catalyzing the hydroxylation of tyrosine into o-diphenols and the oxidation of o-diphenols into o-q...

Noncovalent immobilization of ionic-tagged box-Cu(OAc)2 complex and its application in asymmetric Henry reaction.

Chirality 24(12) , 1092-5, (2012)

Immobilized Cu(OAc)(2)-bis(oxazolines) via hydrogen bonding by SBA-15 was applied to asymmetric Henry reaction, and good enantioselectivities were obtained (up to 83% ee) between 2-methoxybenzaldehyde...

Food protective effects of Periploca sepium oil and its active component against stored food mites.

J. Food Prot. 75(1) , 118-22, (2012)

The aim of this study was to examine the acaricidal activity of Periploca sepium oil and its active component against Tyrophagus putrescentiae. Based on its 50% lethal dose (LD(50) ) value, P. sepium ...

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