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2-乙基己基二苯基磷酸酯

2-乙基己基二苯基磷酸酯用途

用作添加型阻燃剂和阻燃增塑剂，适用于合成树脂与合成橡胶为基料的胶粘剂，可提高耐候性、耐磨性、耐湿性和韧性。

2-乙基己基二苯基磷酸酯名称

[ CAS 号 ]:
1241-94-7

[ 中文名 ]:
2-乙基己基二苯基磷酸酯

[ 英文名 ]:
2-Ethylhexyldiphenyl phosphate

[中文别名 ]:

[英文别名 ]:

2-Ethylhexyl diphenyl phosphate
Diphenyl 2-ethylhexyl phosphate
2-Ethylhexyldiphenylphosphate
phosphoric acid diphenyl 2-ethyl-hexyl ester
Santicizer 141
EINECS 214-987-2
MFCD00059949
Phosflex(R)362
Phosphoric acid,2-ethylhexyl diphenyl ester
2-Ethylhexyldiphenyl phosphate

2-乙基己基二苯基磷酸酯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
421.2±18.0 °C at 760 mmHg

[ 熔点 ]:
-54°C

[ 分子式 ]:
C₂₀H₂₇O₄P

[ 分子量 ]:
362.400

[ 闪点 ]:
222.0±41.6 °C

[ 精确质量 ]:
362.164703

[ PSA ]:
54.57000

[ LogP ]:
6.64

[ 外观性状 ]:
透明至黄色液体

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.522

[ 储存条件 ]:
2-8°C

[ 水溶解性 ]:
Insoluble

2-乙基己基二苯基磷酸酯MSDS

2-乙基己基二苯基磷酸酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TC6125000

CHEMICAL NAME :: Phosphoric acid, 2-ethylhexyl diphenyl ester

CAS REGISTRY NUMBER :: 1241-94-7

BEILSTEIN REFERENCE NO. :: 2568983

LAST UPDATED :: 199710

DATA ITEMS CITED :: 15

MOLECULAR FORMULA :: C20-H27-O4-P

MOLECULAR WEIGHT :: 362.44

WISWESSER LINE NOTATION :: 4Y2&1OPO&OR&OR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TSCAT* Office of Toxic Substances Report. (U.S. Environmental Protection Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460) Volume(issue)/page/year: OTS 206227

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 930 mg/kg

TOXIC EFFECTS :: Behavioral - anticonvulsant Behavioral - tremor Behavioral - muscle weakness

REFERENCE :: TSCAT* Office of Toxic Substances Report. (U.S. Environmental Protection Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460) Volume(issue)/page/year: OTS 206227

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 218 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: IPSTB3 International Polymer Science and Technology. (Rapra Technology Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year: 3,93,1976

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >7900 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 41,291,1977

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 272 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - respiratory stimulation

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 8,170,1953

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 41,291,1977 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 437 gm/kg/2Y-C

TOXIC EFFECTS :: Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 8,170,1953 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.5 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84203 No. of Facilities: 587 (estimated) No. of Industries: 20 No. of Occupations: 16 No. of Employees: 11432 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84203 No. of Facilities: 1223 (estimated) No. of Industries: 33 No. of Occupations: 28 No. of Employees: 21161 (estimated) No. of Female Employees: 4366 (estimated)

2-乙基己基二苯基磷酸酯安全信息

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R50/53

[ 安全声明 (欧洲) ]:
S60-S61

[ 危险品运输编码 ]:
UN 3082

[ RTECS号 ]:
TC6125000

[ 危险类别 ]:
9.0

[ 海关编码 ]:
2919900090

2-乙基己基二苯基磷酸酯合成路线

2-乙基己基二苯基磷酸酯上下游产品

2-乙基己基二苯基磷酸酯上游产品

2-乙基己基二苯基磷酸酯下游产品

2-乙基己基二苯基磷酸酯制备

将2-乙基乙醇加入反应釜，冷却降温到10℃以下，在搅拌下缓缓加入三氯氧磷，加三氯氧磷过程中，湿度不得超过10℃加完后升温，25℃以下进行反应生成二酰氯化物，搅拌下将二酰氯化物在5℃与苯酚钠缓缓混合，升温至40℃进行全酯化反应，反应产物经洗涤、薄膜蒸发、脱色压滤即得成品。

2-乙基己基二苯基磷酸酯海关

[ 海关编码 ]: 2919900090

[ 中文概述 ]:
HS:2919900090 其他磷酸酯及其盐（包括乳磷酸盐）（包括它们的卤化，磺化，硝化和亚硝化衍生物）增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2919900090 other phosphoric esters and their salts, including lactophosphates; their halogenated, sulphonated, nitrated or nitrosated derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

2-乙基己基二苯基磷酸酯文献

Migration from plasticized films into foods. 3. Migration of phthalate, sebacate, citrate and phosphate esters from films used for retail food packaging.

Food Addit. Contam. 5(1) , 9-20, (1988)

A UK survey of plasticizer levels in retail foods (73 samples) wrapped in plasticized films or materials with plasticized coatings has been carried out. A wide range of different food-types packaged i...

Size-dependent atmospheric deposition and inhalation exposure of particle-bound organophosphate flame retardants.

J. Hazard. Mater. 301 , 504-11, (2015)

Atmospheric size-fractionated particles were collected at different heights in an e-waste recycling zone (QY) and urban Guangzhou (GZ), China and analyzed for organophosphate flame retardants (OPFRs)....

[Photometric method of determining di(2-ethylhexyl)phenylphosphate in air].

Gig. Sanit. (8) , 59-60, (1982)

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