己酸丙烯酯

己酸丙烯酯用途

【用途一】
用于配制菠萝及其它果味食用香精
【用途二】
己酸丙烯酯是我国规定暂时允许使用的食用香料，常用于调制草莓、杏子、桃子、甜橙、菠萝、苹果等果香型食用香精和烟用香精。用量按正常生产需要，一般在口香糖中210mg/kg、糖果中32 mg/kg、焙烤食品中25mg/kg、冷饮中11 mg/kg。
【用途三】
己酸烯丙酯是我国规定暂时允许使用的食用香料，常用于调制草莓、杏、桃、甜橙、菠萝、苹果等果香型食用香精和烟用香精，用量按正常生产需要，一般在口香糖中210mg/kg;糖果中32mg/kg；焙烤食品中25mg/kg；冷饮中11mg/kg。
【用途四】
我国GB 2760--1996规定为暂时允许使用的食用香料。主要用于配制菠萝、苹果等水果型香精。
【用途五】
广泛用于配制食用香精、香料、烟用香精，配制菠萝及其他水果香精。也是有机合成的中间体。

己酸丙烯酯名称

[ CAS 号 ]:
123-68-2

[ 中文名 ]:
己酸烯丙酯

[ 英文名 ]:
Allyl caproate

[中文别名 ]:

[英文别名 ]:

EINECS 204-642-4
hexanoic acid allyl ester
hexanoic acid prop-2-enyl ester
Hexanoic acid, allyl ester
2-Propenyl n-hexanoate
Hexanoic acid, 2-propen-1-yl ester
prop-2-enyl hexanoate
MFCD00038339
2-propenyl hexanoate
Allyl n-caproate

己酸丙烯酯物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
186.0±0.0 °C at 760 mmHg

[ 分子式 ]:
C₉H₁₆O₂

[ 分子量 ]:
156.222

[ 闪点 ]:
66.1±0.0 °C

[ 精确质量 ]:
156.115036

[ PSA ]:
26.30000

[ LogP ]:
3.12

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
0.7±0.3 mmHg at 25°C

[ 折射率 ]:
1.429

[ 储存条件 ]:
室温

[ 水溶解性 ]:
PRACTICALLY INSOLUBLE

己酸丙烯酯MSDS

详细MSDS(安全技术说明书)

己酸丙烯酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MO6125000

CHEMICAL NAME :: Hexanoic acid, allyl ester

CAS REGISTRY NUMBER :: 123-68-2

BEILSTEIN REFERENCE NO. :: 1761920

LAST UPDATED :: 199804

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C9-H16-O2

MOLECULAR WEIGHT :: 156.25

WISWESSER LINE NOTATION :: 5VO2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Human

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 218 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity)

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 300 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 280 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Gastrointestinal - changes in structure or function of salivary glands

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 219 gm/kg/2Y-C

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors

MUTATION DATA

TYPE OF TEST :: Gene conversion and mitotic recombination

TEST SYSTEM :: Bacteria - Bacillus subtilis

DOSE/DURATION :: 18 ug/disc

REFERENCE :: OEKSDJ Osaka-furitsu Koshu Eisei Kenkyusho Kenkyu Hokoku, Shokuhin Eisei Hen. Research Reports of the Osaka Prefectural Institute of Public Health, Food Sanitation Section. (Osaka-furitsu Koshu Eisei Kenkyusho, 1-3-69 Nakamichi, Higashinari-ku, Osaka 537, Japan) No.1- 1970- Volume(issue)/page/year: 9,177,1978 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5034 No. of Facilities: 2949 (estimated) No. of Industries: 25 No. of Occupations: 34 No. of Employees: 38592 (estimated) No. of Female Employees: 24656 (estimated)

己酸丙烯酯安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311-H411

[ 警示性声明 ]:
P273-P280-P312

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic

[ 风险声明 (欧洲) ]:
R22;R24;R51/53

[ 安全声明 (欧洲) ]:
S36/37-S45-S61

[ 危险品运输编码 ]:
UN 2810 6.1/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
MO6125000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
29159080

己酸丙烯酯合成路线

详细合成路线

己酸丙烯酯上下游产品

己酸丙烯酯上游产品

己酸丙烯酯下游产品

己酸丙烯酯制备

1.己酸与烯丙醇在硫酸催化下直接酯化，然后经中和；水洗；精馏而得成品。

2.由己酸与烯丙醇酯化，经中和、水洗、干燥、精制而得。

己酸丙烯酯海关

[ 海关编码 ]: 2915900090

[ 中文概述 ]:
2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

己酸丙烯酯文献

Olfactory event-related potentials in patients with brain tumors.

Clin. Neurophysiol. 112(8) , 1523-30, (2001)

The aim of the study was to determine how odor processing is altered in patients with unilateral supratentorial brain tumors.Olfactory event-related potentials (OERPs) were evaluated in 10 patients wi...

Robust dismissal of a claim on chemical sensitisation.

Lancet 339(8788) , 297, (1992)

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