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(1,5-环辛二烯)氯铑(I)二聚体

(1,5-环辛二烯)氯铑(I)二聚体用途

【用途1】
1,3-二烯和激活的烃反应的催化剂及制备手性复合物。耦合反应；不对称氢化反应；硼氢化反应。

(1,5-环辛二烯)氯铑(I)二聚体名称

[ CAS 号 ]:
12092-47-6

[ 中文名 ]:
(1,5-环辛二烯)氯铑(I)二聚体

[ 英文名 ]:
(1,5-Cyclooctadiene)rhodium chloride dimer

[中文别名 ]:

[英文别名 ]:

Bis(1,5-cyclooctadiene)dirhodium(I) Dichloride
(1Z,5Z)-cycloocta-1,5-diene,rhodium,dichloride
(1,5-Cyclooctadiene)rhodium chloride dimer
MFCD00012415
1,5-Cyclooctadiene - chlororhodium (1:1)
1,5-Cyclooctadiene Rhodium(I) Chloride Dimer
EINECS 235-157-6
Chloro(1,5-Cyclooctadiene)Rhodium(I) Dimer
(1Z,5Z)-Cycloocta-1,5-diene - chlororhodium (1:1)
Chloro(1,5-cyclooctadiene)rhodium(I)dimer

(1,5-环辛二烯)氯铑(I)二聚体物理化学性质

[ 沸点 ]:
153.5ºC at 760mmHg

[ 熔点 ]:
255ºC (dec.)

[ 分子式 ]:
C₁₆H₂₄Cl₂Rh₂

[ 分子量 ]:
493.079

[ 闪点 ]:
31.7ºC

[ 精确质量 ]:
491.936523

[ 外观性状 ]:
黄色-橙色结晶粉末

[ 储存条件 ]:
2-8°C

[ 稳定性 ]:
hygroscopic

[ 水溶解性 ]:
Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.

(1,5-环辛二烯)氯铑(I)二聚体MSDS

(1,5-环辛二烯)氯铑(I)二聚体安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

(1,5-环辛二烯)氯铑(I)二聚体合成路线

(1,5-环辛二烯)氯铑(I)二聚体上下游产品

(1,5-环辛二烯)氯铑(I)二聚体上游产品

(1,5-环辛二烯)氯铑(I)二聚体下游产品

(1,5-环辛二烯)氯铑(I)二聚体文献

The use of a [4 + 2] cycloaddition reaction for the preparation of a series of 'tethered' Ru(II)-diamine and aminoalcohol complexes.

Org. Biomol. Chem. 5 , 1093, (2007)

A series of catalysts have been prepared for use in the asymmetric transfer hydrogenation of ketones. The complexes were prepared using a [4 + 2] cycloaddition reaction at a key step in the reaction s...

Pure Appl. Chem. 66 , 1509, (1994)

Tetrahedron Asymmetry 4 , 2279, (1993)

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