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丙森锌

丙森锌用途

Propineb (Zinc propylenebis) 是一种广泛用于水果和蔬菜病害的化合物,其具有抗植物真菌疾病的广谱活性。

丙森锌名称

[ CAS 号 ]:
12071-83-9

[ 中文名 ]:
丙森锌

[ 英文名 ]:
propineb

[中文别名 ]:

[英文别名 ]:

[Propylenebis(dithiocarbamato)]zinc
ZINC TRIFLUOROACETATE
trifluoro-acetic acid,zinc-trifluoroacetate
EINECS 235-134-0
Zinc 1,2-propanediyldicarbamodithioate
Zinc propane-1,2-diyldicarbamodithioate
MFCD00055491
zinc rifluoroacetate

丙森锌生物活性

[ 描述 ]:

Propineb (Zinc propylenebis) 是一种广泛用于水果和蔬菜病害的化合物,其具有抗植物真菌疾病的广谱活性。

[ 相关类别 ]:

研究领域 >> 感染

信号通路 >> 抗感染 >> 细菌

[体内研究]

Propineb(Zrate propylenebis)具有中等至低的急性毒性,在大鼠中具有特定的致甲状腺肿毒作用。长期接触,口服或吸入与致癌性,致畸性,生殖系统功能失常和生命体质畸形有关[2]。

[参考文献]

[1]. Viviani B, et al. Dithiocarbamate propineb induces acetylcholine release through cytoskeletal actin depolymerization in PC12 cells. Toxicol Lett. 2008 Nov 10;182(1-3):63-8.

[2]. Kazos EA, et al. Determination of dithiocarbamate fungicide propineb and its main metabolite propylenethiourea in airborne samples. Chemosphere. 2007 Aug;68(11):2104-10.

丙森锌物理化学性质

[ 沸点 ]:
315.4ºC at 760 mmHg

[ 熔点 ]:
160ºC

[ 分子式 ]:
C₅H₈N₂S₄Zn

[ 分子量 ]:
289.77

[ 闪点 ]:
144.5ºC

[ 精确质量 ]:
287.886169

[ PSA ]:
165.84000

[ LogP ]:
1.76530

[ 外观性状 ]:
白色或淡黄色粉末

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

丙森锌毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: ZH4950000

CHEMICAL NAME :: Zinc, (N,N'-propylene-1,2-bis(dithiocarbamate))

CAS REGISTRY NUMBER :: 12071-83-9

LAST UPDATED :: 199409

DATA ITEMS CITED :: 12

WISWESSER LINE NOTATION :: SUYS&MY1&1MYS&US &ZN-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 8500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >693 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 2300 mg/kg

SEX/DURATION :: female 11 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Specific Developmental Abnormalities - eye/ear Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 2300 mg/kg

SEX/DURATION :: female 11 day(s) after conception

TOXIC EFFECTS :: Reproductive - Specific Developmental Abnormalities - musculoskeletal system Reproductive - Specific Developmental Abnormalities - homeostasis

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 1 gm/kg

SEX/DURATION :: female 6-15 day(s) after conception

TOXIC EFFECTS :: Reproductive - Specific Developmental Abnormalities - other developmental abnormalities

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 2 gm/kg

SEX/DURATION :: female 6-15 day(s) after conception

TOXIC EFFECTS :: Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

MUTATION DATA

TEST SYSTEM :: Rodent - rat

DOSE/DURATION :: 2600 mg/kg/5D (Intermittent)

REFERENCE :: PRKHDK Problemi na Khigienata. Problems in Hygiene. (Durzhavno Izdatel'stvo Meditsina i Fizkultura, Pl. Slaveikov 11, Sofia, Bulgaria) V.1- 1975- Volume(issue)/page/year: 4,151,1979

丙森锌安全信息

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
51/53

[ 安全声明 (欧洲) ]:
60-61

[ 危险品运输编码 ]:
UN3077 9/PG 3

[ RTECS号 ]:
ZH4950000

[ 包装等级 ]:
III

[ 海关编码 ]:
2930200012

丙森锌海关

[ 海关编码 ]: 2930200012

[ 中文概述 ]:
2930200012 威百亩、代森钠、丙森锌、福美铁等〔包括福美锌、代森福美锌、安百亩〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2930200012 iron(iii) dimethylcarbamodithioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

丙森锌文献

[Teratogenic and goitrogenic activity of propineb and propylenethiourea in the rat].

Boll. Soc. Ital. Biol. Sper. 61(2) , 271-8, (1985)

The teratogenic and goitrogenic effects of Propineb, dithiocarbamate pesticide and Propylenthiourea (PLTU), its metabolite and degradation product have been studied. The aim of this study was to show ...

Dithiocarbamate pesticides: activity of Propineb in the micronucleus test in mice.

Mutat. Res. 135(3) , 193-7, (1984)

The possible clastogenic activity of Propineb, Propineb technical grade and of its main metabolite, propylene-thiourea (PLTU), was investigated by the micronucleus test in mice according to Schmid. No...

Determination of dithiocarbamate fungicide propineb and its main metabolite propylenethiourea in airborne samples.

Chemosphere 68(11) , 2104-10, (2007)

A simple, rapid and sensitive GC-MS method for the determination of dithiocarbamate fungicide propineb [polymeric zinc propylenebis (dithiocarbamate)] and an improved HPLC procedure for the simultaneo...

更多文献

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丙森锌