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(S)-叔亮氨醇

(S)-叔亮氨醇名称

[ CAS 号 ]:
112245-13-3

[ 中文名 ]:
L-叔亮氨醇

[ 英文名 ]:
(S)-tert-Leucinol

[中文别名 ]:

[英文别名 ]:

(R)-(−)-tert-Leucinol
(2R)-2-amino-3,3-dimethylbutan-1-ol
MFCD00192250
(R)-tert-Leucinol
(R)-2-Amino-3,3-dimethylbutan-1-ol
(2S)-2-Amino-3,3-dimethyl-1-butanol
L-t-butyl leucinol
1-Butanol, 2-amino-3,3-dimethyl-, (2S)-
H-TLE-OL
L-T-LEUCINOL

(S)-叔亮氨醇物理化学性质

[ 密度 ]:
0.9

[ 沸点 ]:
198.5±13.0 °C at 760 mmHg

[ 熔点 ]:
30-34ºC(lit.)

[ 分子式 ]:
C₆H₁₅NO

[ 分子量 ]:
117.189

[ 闪点 ]:
90 ºC

[ 精确质量 ]:
117.115364

[ PSA ]:
46.25000

[ LogP ]:
0.27

[ 外观性状 ]:
白色结晶低熔点块

[ 蒸汽压 ]:
0.1±0.8 mmHg at 25°C

[ 折射率 ]:
1.452

[ 储存条件 ]:
2-8°C

[ 水溶解性 ]:
可溶于：甲醇

(S)-叔亮氨醇MSDS

(S)-叔亮氨醇安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
1325.0

[ WGK德国 ]:
3

[ 危险类别 ]:
4.1

[ 海关编码 ]:
2922199090

(S)-叔亮氨醇合成路线

(S)-叔亮氨醇上下游产品

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(S)-叔亮氨醇下游产品

(S)-叔亮氨醇海关

[ 海关编码 ]: 2922199090

[ 中文概述 ]:
2922199090. 其他氨基醇及其醚，酯和它们的盐（但含一种以上含氧基的除外）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ Summary ]:
2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

(S)-叔亮氨醇文献

Synthesis and Properties of a Novel Pyridineoxazoline Containing Optically Active Helical Polymer as a Catalyst Ligand for Asymmetric Diels-Alder Reaction.

Chirality 27 , 523-31, (2015)

A novel pyridineoxazoline (PyOx) containing helical polymer, poly{(-)-(S)-4-tert-butyl-2-[5-(4-tert-butylphenyl)-3-vinylpyridin-2-yl]-oxazoline} (PA), was designed and synthesized to approach the effe...

SimplePHOX, a readily available chiral ligand system for iridium-catalyzed asymmetric hydrogenation.

Org. Lett. 6 , 2023-2026, (2004)

[reaction: see text] New Ir-SimplePHOX complexes Ir-6-Ir-9 catalyze the quantitative, highly enantioselective hydrogenation of a range of unfunctionalized and functionalized olefins. Synthesis, cataly...

Tetrahedron Lett. 45 , 5649, (2004)

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