Organic Letters 2004-06-10

SimplePHOX, a readily available chiral ligand system for iridium-catalyzed asymmetric hydrogenation.

Sebastian P Smidt, Frederik Menges, Andreas Pfaltz

文献索引：Org. Lett. 6 , 2023-2026, (2004)

全文：HTML全文

摘要

[reaction: see text] New Ir-SimplePHOX complexes Ir-6-Ir-9 catalyze the quantitative, highly enantioselective hydrogenation of a range of unfunctionalized and functionalized olefins. Synthesis, catalytic results, and X-ray crystal structures are presented here.