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油胺

油胺用途

【用途一】
有机中间体及纺织助剂
【用途二】
本品可用作化学纤维的柔软剂，防水剂。亦可作染料，涂料分散剂，金属防锈剂。

油胺名称

[ CAS 号 ]:
112-90-3

[ 中文名 ]:
油胺

[ 英文名 ]:
Oleylamine

[中文别名 ]:

[英文别名 ]:

9-Octadecen-1-amine, (9Z)-
(9Z)-Octadec-9-en-1-amine
Kelochlorden
EINECS 204-015-5
cis-9-Octadecenylamine
diethyl 4-oxo-4H-pyran-2,6-dicarboxylate
diethyl chelidonate
Kemamine P 989D
Chelidonsaeure-diaethylester
oleyl amine

油胺物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
364.4±21.0 °C at 760 mmHg

[ 熔点 ]:
15-22ºC

[ 分子式 ]:
C₁₈H₃₇N

[ 分子量 ]:
267.493

[ 闪点 ]:
154.4±0.0 °C

[ 精确质量 ]:
267.292603

[ PSA ]:
26.02000

[ LogP ]:
7.85

[ 外观性状 ]:
米色糊或粉末

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.464

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 稳定性 ]:
Stable. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents.

[ 水溶解性 ]:
insoluble

油胺MSDS

油胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RG4130000

CHEMICAL NAME :: 9-Octadecenylamine, (Z)-

CAS REGISTRY NUMBER :: 112-90-3

BEILSTEIN REFERENCE NO. :: 1723960

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C18-H37-N

MOLECULAR WEIGHT :: 267.56

WISWESSER LINE NOTATION :: Z9U9

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 888 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DZZEA7 Deutsche Zahnaerztliche Zeitschrift. (Carl Hanser Verlag, Postfach 860420, D-8000 Munich 86, Fed. Rep. Ger.) V.1- 1946- Volume(issue)/page/year: 35,1070,1980 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 431 mg/kg/9D-I

TOXIC EFFECTS :: Behavioral - food intake (animal) Skin and Appendages - dermatitis, other (after systemic exposure) Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0525400 ** REPRODUCTIVE DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 800 mg/kg

SEX/DURATION :: female 9 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)

REFERENCE :: DZZEA7 Deutsche Zahnaerztliche Zeitschrift. (Carl Hanser Verlag, Postfach 860420, D-8000 Munich 86, Fed. Rep. Ger.) V.1- 1946- Volume(issue)/page/year: 32,861,1977

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

DOSE :: 400 mg/kg

SEX/DURATION :: female 9 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Specific Developmental Abnormalities - other developmental abnormalities

REFERENCE :: DZZEA7 Deutsche Zahnaerztliche Zeitschrift. (Carl Hanser Verlag, Postfach 860420, D-8000 Munich 86, Fed. Rep. Ger.) V.1- 1946- Volume(issue)/page/year: 32,861,1977 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83831 No. of Facilities: 490 (estimated) No. of Industries: 7 No. of Occupations: 7 No. of Employees: 3073 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83831 No. of Facilities: 1614 (estimated) No. of Industries: 11 No. of Occupations: 8 No. of Employees: 26708 (estimated) No. of Female Employees: 2965 (estimated)

油胺安全信息

[ 符号 ]:

GHS05, GHS07, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H304-H314-H335-H373-H410

[ 警示性声明 ]:
P260-P280-P301 + P310-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ 靶器官 ]:
Gastrointestinal tract, Immune system, Liver

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R22;R34

[ 安全声明 (欧洲) ]:
S24/25-S26

[ 危险品运输编码 ]:
UN 2735

[ WGK德国 ]:
2

[ RTECS号 ]:
RG4130000

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2921199090

油胺合成路线

油胺上下游产品

油胺上游产品

油胺下游产品

油胺制备

将 100 kg 油酸投入反应釜中，加热熔化，在搅拌下升温，当物料达到 180 ℃ 左右，开始通氨气。氨气从反应釜底部通过分布器进入料液。快速搅拌加强气相与液相接触。副产物水和末瓜的氨气通过冷凝器进入回收装置。当氨通入量为 200 kg 时，检测排出的气相中有无水，如果气体中无水，即确定反应到终点。停止通氮。趁热出料，冷却成型。用乙醇作溶剂进行重结晶得精品。

油胺海关

[ 海关编码 ]: 2921199090

[ 中文概述 ]:
2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

油胺文献

Amelioration of radiation-induced oral cavity mucositis and distant bone marrow suppression in fanconi anemia Fancd2-/- (FVB/N) mice by intraoral GS-nitroxide JP4-039.

Radiat. Res. 182(1) , 35-49, (2014)

The altered DNA damage response pathway in patients with Fanconi anemia (FA) may increase the toxicity of clinical radiotherapy. We quantitated oral cavity mucositis in irradiated Fanconi anemia Fancd...

Surface modification-induced phase transformation of hexagonal close-packed gold square sheets.

Nat. Commun. 6 , 6571, (2015)

Conventionally, the phase transformation of inorganic nanocrystals is realized under extreme conditions (for example, high temperature or high pressure). Here we report the complete phase transformati...

Electrocatalytic and Photocatalytic Hydrogen Production from Acidic and Neutral-pH Aqueous Solutions Using Iron Phosphide Nanoparticles.

ACS Nano 8(11) , 11101-7, (2014)

Nanostructured transition-metal phosphides have recently emerged as Earth-abundant alternatives to platinum for catalyzing the hydrogen-evolution reaction (HER), which is central to several clean ener...

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油胺