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辛胺

辛胺用途

【用途一】
用作农药、表面活性剂、医药合成的中间体
【用途二】
用于有机合成
【用途三】
有机合成。生化研究。

辛胺名称

[ CAS 号 ]:
111-86-4

[ 中文名 ]:
辛胺

[ 英文名 ]:
Octylamine

[中文别名 ]:

[英文别名 ]:

Octan-1-amine
mono-n-octyl amine
1-Aminooctane
mononitrobenzoylurea
EINECS 203-916-0
n-octyl amine
Caprylamine
1-octylamine
6-Nitrobenzoyleneurea
Octylamine

辛胺物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
179.4±3.0 °C at 760 mmHg

[ 熔点 ]:
−5-−1 °C(lit.)

[ 分子式 ]:
C₈H₁₉N

[ 分子量 ]:
129.243

[ 闪点 ]:
62.8±0.0 °C

[ 精确质量 ]:
129.151749

[ PSA ]:
26.02000

[ LogP ]:
3.06

[ 外观性状 ]:
透明液体带有一种像氨一样的气味

[ 蒸汽压 ]:
0.9±0.3 mmHg at 25°C

[ 折射率 ]:
1.432

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 水溶解性 ]:
0.2 g/L (25 ºC)

辛胺MSDS

辛胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RG8050000

CHEMICAL NAME :: 1-Octanamine

CAS REGISTRY NUMBER :: 111-86-4

BEILSTEIN REFERENCE NO. :: 1679227

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C8-H19-N

MOLECULAR WEIGHT :: 129.28

WISWESSER LINE NOTATION :: Z8

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-1085-0569 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 50 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-1085-0569

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD691-490

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 18 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: BJPCAL British Journal of Pharmacology and Chemotherapy. (London, UK) V.1-33, 1946-68. For publisher information, see BJPCBM. Volume(issue)/page/year: 7,42,1952

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2 gm/kg

TOXIC EFFECTS :: Behavioral - altered sleep time (including change in righting reflex) Behavioral - somnolence (general depressed activity)

REFERENCE :: EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-1085-0569 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M3277 No. of Facilities: 103 (estimated) No. of Industries: 3 No. of Occupations: 13 No. of Employees: 3653 (estimated)

辛胺安全信息

[ 符号 ]:

GHS02, GHS05, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H301 + H311-H314-H332-H335-H410

[ 警示性声明 ]:
P210-P280-P301 + P310 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R20/21/22;R35;R50

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S61-S29

[ 危险品运输编码 ]:
UN 2735 8/PG 2

[ WGK德国 ]:
2

[ RTECS号 ]:
RG8050000

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
29211980

辛胺合成路线

辛胺上下游产品

辛胺上游产品

辛胺下游产品

辛胺制备

1. 由辛酸与氨反应、脱水和加氢制备。

2. 烟草：OR，18。

辛胺海关

[ 海关编码 ]: 2921199090

[ 中文概述 ]:
2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

辛胺文献

Surface modification-induced phase transformation of hexagonal close-packed gold square sheets.

Nat. Commun. 6 , 6571, (2015)

Conventionally, the phase transformation of inorganic nanocrystals is realized under extreme conditions (for example, high temperature or high pressure). Here we report the complete phase transformati...

Protic ionic liquids (PILs) nanostructure and physicochemical properties: development of high-throughput methodology for PIL creation and property screens.

Phys. Chem. Chem. Phys. 17(4) , 2357-65, (2014)

A high-throughput approach was developed in order to prepare and dry a series of protic ionic liquids (PILs) from 48 Brønsted acid-base combinations. Many combinations comprised an alkyl carboxylic ac...

Mosquito odorant receptor for DEET and methyl jasmonate.

Proc. Natl. Acad. Sci. U. S. A. 111(46) , 16592-7, (2014)

Insect repellents are important prophylactic tools for travelers and populations living in endemic areas of malaria, dengue, encephalitis, and other vector-borne diseases. DEET (N,N-diethyl-3-methylbe...

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辛胺