The porphyrinogen-porphodimethene relationship leading to novel synthetic methodologies focused on the modification and functionalization of the porphyrinogen …
…, E Solari, R Scopelliti, C Floriani, N Re
文献索引：Bonomo, Lucia; Solari, Euro; Scopelliti, Rosario; Floriani, Carlo; Re, Nazzareno Journal of the American Chemical Society, 2000 , vol. 122, # 22 p. 5312 - 5326
The general synthetic methods presented in this paper make available, on a preparative scale, unprecedented porphyrinogen-derived skeletons, including their functionalization at the meso positions. The stepwise dealkylation of meso-octaalkylporphyrinogen R8N4H4 [R= Et, 1; R= Bun, 2] was chemically, mechanistically, and structurally followed until the formation of porphomethene and porphodimethene derivatives 5-13, obtained with a ...
