Reformatsky reaction of?-chloroesters with carbonyl compounds with commercially available zinc

SP Chavan, K Shivasankar…

文献索引：Chavan, Subhash P.; Shivasankar; Sivappa Journal of Chemical Research, 2004 , # 6 p. 406 - 407

被引用次数: 3

摘要

Refomatsky reaction.12 This reaction has also been performed with Rieke zinc but the yields of the reaction are moderate to very low13 to be of any utility on a preparative scale. The utility of -chloroester to participate in the Reformatsky reaction seems almost non-existent inspite of its ready availability, stability cost-effectiveness as well as its less hazardous nature as compared to the corresponding bromoesters. ... We now report the condensation of -chloroesters ...

~70%

~83%

~80%

Carbon-carbon bond-forming reactions using cerium metal or o...

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