Carbon-carbon bond-forming reactions using cerium metal or organocerium (III) reagents

T Imamoto, T Kusumoto, Y Tawarayama…

文献索引：Imamoto, Tsuneo; Kusumoto, Tetsuo; Tawarayama, Yoshinori; Sugiura, Yasushi; Mita, Takeshi; et al. Journal of Organic Chemistry, 1984 , vol. 49, # 21 p. 3904 - 3912

全文：HTML全文

被引用次数: 367

摘要

OV-225 at 175" C) a 3% recovery of the starting cyclohexenone and the two diastereomeric tricyclooctanones: 2 9 0.126 g (20%); colorless oil; IR 1715, 1642 cm-';'H NMR (CDC13) 6 4.53 (m, 2 H), 2.70-1.73 (m, 5 H), 1.50 (bs, 3 H), 1.26 (s, 3 H), 1.18 (s, 3 H), 0.90 (s, 3 H); mass spectrum, m/z (relative intensity) 204 (M+, 78), 189 (57), 176 (62), 161 (41), 149 (54), 136 (loo), 121 (loo), 109 (loo), 96 (1001, 94 (loo), 82 (56), 68 (36), 51 (78); high-resolution ...