The Journal of Organic Chemistry

The Cracking and Rearrangement of Diallyl Ketals to α-Allyl Ketones

NB Lorette, WL Howard

文献索引：Lorette,N.B.; Howard,W.L. Journal of Organic Chemistry, 1961 , vol. 26, p. 3112 - 3115

被引用次数: 39

摘要

Srveral diallyl ketals were cravked in the presencr of acid and rearranged to alpha allyl- substituted ketones in high yields. The u5e of 2, 2-dimethoxypropune made possible the preparation of alpha allyl-substituted ketones from ketones and allvl alcohol without iqolation of thr intermediate diallvl ketxl.:

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