The Journal of Organic Chemistry

The Cracking and Rearrangement of Diallyl Ketals to α-Allyl Ketones

NB Lorette, WL Howard

Index: Lorette,N.B.; Howard,W.L. Journal of Organic Chemistry, 1961 , vol. 26, p. 3112 - 3115

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Citation Number: 39

Abstract

Srveral diallyl ketals were cravked in the presencr of acid and rearranged to alpha allyl- substituted ketones in high yields. The u5e of 2, 2-dimethoxypropune made possible the preparation of alpha allyl-substituted ketones from ketones and allvl alcohol without iqolation of thr intermediate diallvl ketxl.:

 Related Synthetic Route
N/A Structure

99992-69-5

N/A

~%

6-Hepten-3-one,4-methyl- Structure

26118-97-8

6-Hepten-3-one,...

CYCLOHEXANONE DIALLYLACETAL Structure

53608-84-7

CYCLOHEXANONE D...

~%

2,2-Diallylcyclohexanone Structure

5277-36-1

2,2-Diallylcycl...

1-(2-propen-1-yloxy)cyclohexene Structure

79643-88-2

1-(2-propen-1-y...

~%

2,2-Diallylcyclohexanone Structure

5277-36-1

2,2-Diallylcycl...

2-Allylcyclohexanone Structure

94-66-6

2-Allylcyclohexanone

Allyl alcohol Structure

107-18-6

Allyl alcohol

~%

2,2-Diallylcyclohexanone Structure

5277-36-1

2,2-Diallylcycl...

1,1-bis(prop-2-enoxy)cyclopentane Structure

62322-44-5

1,1-bis(prop-2-...

~%

2-prop-2-enylcyclopentan-1-one Structure

30079-93-7

2-prop-2-enylcy...

Allyl alcohol Structure

107-18-6

Allyl alcohol

Acetophenone Structure

98-86-2

Acetophenone

~%

4-Penten-1-one,1-phenyl- Structure

3240-29-7

4-Penten-1-one,...

5,5-bis-allyloxy-hex-1-ene Structure

860389-04-4

5,5-bis-allylox...

~%

3-prop-2-enylhex-5-en-2-one Structure

75265-80-4

3-prop-2-enylhe...

1-Hexen-5-one Structure

109-49-9

1-Hexen-5-one

~%

3-prop-2-enylhex-5-en-2-one Structure

75265-80-4

3-prop-2-enylhe...


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