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Journal of the American Chemical Society

Reactions of Tricyclopropylcarbinol Derivatives

H Hart, PA Law

文献索引:Hart,H.; Law,P.A. Journal of the American Chemical Society, 1962 , vol. 84, p. 2462 - 2463

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被引用次数: 16

摘要

Some time ago we reported3 that a second cyclopropyl group was nearly as effective as the first in accelerating the solvolysis of cyclopropylcarbinyl derivatives. Thus, the ratios of the solvolysis rates Io: 11: I2 (X= p-nitrobenzoate) in 80% aqueous dioxane at GOO were 1: 246: 23,500.? it the time, we were unsuccessful in attempts to