Ruthenium??Catalyzed Hydroarylation of Methylenecyclopropanes through C H Bond Cleavage: Scope and Mechanism

L Ackermann, SI Kozhushkov…

文献索引：Ackermann, Lutz; Kozhushkov, Sergei I.; Yufit, Dmitry S. Chemistry - A European Journal, 2012 , vol. 18, # 38 p. 12068 - 12077

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被引用次数: 32

摘要

Abstract Intermolecular hydroarylation reactions of highly strained methylenecyclopropanes 2-phenylmethylenecyclopropane (1), 2, 2-diphenylmethylenecyclopropane (2), methylenespiropentane (3), bicyclopropylidene (4),(dicyclopropylmethylene) cyclopropane (5), and benzhydrylidenecyclopropane (6) through C [BOND] H bond functionalization of 2- phenylpyridine (7 a) and other arenes with directing groups were studied. The reaction ...