Cationic hydrogenation of benzyl alcohols and arylethylenes using acridane derivatives as hindered NADH models

S Singh, S Chhina, VK Sharma…

文献索引：Singh, Serjinder; Chhina, Sarbjeet; Sharma, Vijay K.; Sachdev, Satbir S. Journal of the Chemical Society, Chemical Communications, 1982 , # 8 p. 453 - 454

全文：HTML全文

被引用次数: 40

摘要

Secondary and tertiary benzyl alcohols and arylethylenes are efficiently reduced by acridane derivatives (1 ) in the presence of trifluoroacetic acid in dichloromethane. ... In steroid biosynthesis, reduction of double bonds usually involves1 protonation and reduction of the incipient carbenium ion catalysed by enzymes possessing NADH as cofactor. We report a reaction in which benzyl alcohols (2) and arylethy- lenes (3) are reduced cleanly at room ...