Temperature and pressure dependence of the rate constant for the HO2+ NO reaction

JV Seeley, RF Meads, MJ Elrod…

文献索引：Seeley, John V.; Meads, Roger F.; Elrod, Matthew J.; Molina, Mario J. Journal of Physical Chemistry, 1996 , vol. 100, # 10 p. 4026 - 4031

全文：HTML全文

被引用次数: 48

摘要

The rate constant for the reaction HO2+ NO→ OH+ NO2 has been measured using the turbulent flow technique with high-pressure chemical ionization mass spectrometry for the detection of reactants and products. At room temperature, the rate constant was found to be independent of pressure between 70 and 190 Torr of N2 and given by (8.0±0.5)× 10-12 cm3 molecule-1 s-1. The temperature dependence of the rate constant was investigated ...