The Reaction of Oxymercurials with Active Methylene Compounds and the Demercuration of the Resulting Mercurials with Acid and Base

K Ichikawa, O Itoh, T Kawamura…

文献索引：Ichikawa,K. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 447 - 452

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被引用次数: 38

摘要

The reaction of oxymercurials with active methylene compounds has been studied in acetic acid, methanol, ethanol, and 2-propanol containing perchloric acid. Active methylene compounds, substituted with alkyls and aralkyls containing mercury, have been obtained in good yields. This reaction proceeds readily in between the oxymercurials from 1-olefins and the active methylene compounds whose keto-enol equilibria are on the side of the enol ...