Characterizing ionic liquids as reaction media through a chemical probe

…, M Fagnoni, A Maia, D Landini, A Albini

文献索引：Dichiarante, Valentina; Betti, Cecilia; Fagnoni, Maurizio; Maia, Angelamaria; Landini, Dario; Albini, Angelo Chemistry - A European Journal, 2007 , vol. 13, # 6 p. 1834 - 1841

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被引用次数: 14

摘要

Abstract The triplet N, N-dimethylaminophenyl cation, a highly reactive but chemospecific electrophile, has been used as a probe for characterizing the properties of reaction media for a series of imidazolium ILs. With the N-hexyl-N-methyl imidazolium derivatives (not with the N-butyl analogues), hydrogen transfer leading to the aniline was the main process. Trapping by iodide occurred with an inverse dependence on viscosity. Trapping by π ...