Organic Letters

Smooth synthesis of aryl-and alkylanilines by photoheterolysis of haloanilines in the presence of aromatics and alkenes

M Fagnoni, M Mella, A Albini

文献索引：Fagnoni, Maurizio; Mella, Mariella; Albini, Angelo Organic Letters, 1999 , vol. 1, # 8 p. 1299 - 1301

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被引用次数: 43

摘要

Irradiation of 4-chloro-N, N-dimethylaniline in acetonitrile in the presence of benzene and of various alkenes leads to heterolytic dehalogenation and trapping of the cation. 4- (Dimethylamino) biphenyl is formed in the first case, while with alkenes β- chloroalkylanilines, stilbenes, or allylanilines are obtained depending on the alkene structure. 4-Fluoroaniline is similarly dehalogenated.