Journal of the American Chemical Society 2012-02-01

Cis-selective ring-opening metathesis polymerization with ruthenium catalysts.

Benjamin K Keitz, Alexey Fedorov, Robert H Grubbs

文献索引：J. Am. Chem. Soc. 134 , 2040-2043, (2012)

摘要

Cis-selective ring-opening metathesis polymerization of several monocyclic alkenes as well as norbornene and oxanorbornene-type monomers using a C-H activated, ruthenium-based metathesis catalyst is reported. The cis content of the isolated polymers depended heavily on the monomer structure and temperature. A cis content as high as 96% could be obtained by lowering the temperature of the polymerization.© 2012 American Chemical Society

结构式	名称/CAS号	分子式	全部文献
	[2-(1-甲基乙氧基-O)苯基甲基-C](硝酸基-O,O′){rel-(2R,5R,7R)-金刚烷-2,1-二基[3-(2,4,6-三甲基苯基)-1-咪唑烷基-2-基亚基]}钌, Grubbs′ Z-选择性催化剂, Grubbs Z 选择性复分解催化剂, Grubbs 催化剂 C633, [2-(1-甲基乙氧基-O)苯基甲基-C](硝酸基-O,O′){rel-(2R,5R,7S)-三环[3.3.1.1 3,7]癸烷-2,1-二基[3-(2,4,6-三甲基苯基)-1-咪唑烷基-2-基亚基]}钌 CAS:1352916-84-7	C₃₂H₄₁N₃O₄Ru

Improved ruthenium catalysts for Z-selective olefin metathes...
2012-01-11
[J. Am. Chem. Soc. 1st ed., 134 , 693-699, (2012)]

Cis-selective ring-opening metathesis polymerization with ruthenium catalysts.

摘要

相关化合物