Journal of the American Chemical Society 2012-02-01

Cis-selective ring-opening metathesis polymerization with ruthenium catalysts.

Benjamin K Keitz, Alexey Fedorov, Robert H Grubbs

Index: J. Am. Chem. Soc. 134 , 2040-2043, (2012)

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Abstract

Cis-selective ring-opening metathesis polymerization of several monocyclic alkenes as well as norbornene and oxanorbornene-type monomers using a C-H activated, ruthenium-based metathesis catalyst is reported. The cis content of the isolated polymers depended heavily on the monomer structure and temperature. A cis content as high as 96% could be obtained by lowering the temperature of the polymerization.© 2012 American Chemical Society