Organic Letters 2005-07-07

Nickel-catalyzed addition of P(O)-H bonds to propargyl alcohols: one-pot generation of phosphinoyl 1,3-butadienes.

Li-Biao Han, Yutaka Ono, Hideaki Yazawa

文献索引：Org. Lett. 7 , 2909, (2005)

摘要

[reaction: see text] Diphenylphosphine oxide and related P(O)H compounds react with propargyl alcohols at room temperature in the presence of a catalytic amount of Ni(0) complex and Ph(2)P(O)OH to produce high yields of phosphinoyl 1,3-dienes though an efficient in situ dehydration process.

结构式	名称/CAS号	分子式	全部文献
	二苯基磷氧 CAS:4559-70-0	C₁₂H₁₁OP

Edwards, M. L.; Stemerick, D. M. et al.
[Tetrahedron Lett. 31 , 5571, (1990)]

Kurz, L.; Lee, G.; Morgans, D. et al.
[Tetrahedron Lett. 31 , 632, (1990)]

Alcock, N. W.; Brown, J. M.; Hulmes, D. I.
[Tetrahedron Asymmetry 4 , 743, (1993)]

Efficient and selective nickel-catalyzed addition of H-P(O) ...
2004-04-28
[J. Am. Chem. Soc. 126 , 5080, (2004)]

Nickel-catalyzed addition of P(O)-H bonds to propargyl alcohols: one-pot generation of phosphinoyl 1,3-butadienes.

摘要

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