Organic Letters 2005-07-07

Nickel-catalyzed addition of P(O)-H bonds to propargyl alcohols: one-pot generation of phosphinoyl 1,3-butadienes.

Li-Biao Han, Yutaka Ono, Hideaki Yazawa

Index: Org. Lett. 7 , 2909, (2005)

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Abstract

[reaction: see text] Diphenylphosphine oxide and related P(O)H compounds react with propargyl alcohols at room temperature in the presence of a catalytic amount of Ni(0) complex and Ph(2)P(O)OH to produce high yields of phosphinoyl 1,3-dienes though an efficient in situ dehydration process.

Structure	Name/CAS No.	Molecular Formula	Articles
	Diphenylphosphine oxide CAS:4559-70-0	C₁₂H₁₁OP

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Efficient and selective nickel-catalyzed addition of H-P(O) ...
2004-04-28
[J. Am. Chem. Soc. 126 , 5080, (2004)]

Nickel-catalyzed addition of P(O)-H bonds to propargyl alcohols: one-pot generation of phosphinoyl 1,3-butadienes.

Abstract

Related Compounds