Mechanistic Investigation of a Novel Vitamin B12-Catalyzed Carbon-Carbon Bond Forming Reaction, the Reductive Dimerization of Arylalkenes

J Shey, CM McGinley, KM McCauley…

文献索引：Journal of Organic Chemistry, , vol. 67, # 3 p. 837 - 846

被引用次数: 37

摘要

... The Journal of ... J. Org. Chem. ... The transformation employs catalytic vitamin B 12 and an auxiliary reductant such as Zn or Ti(III)citrate and can be carried out at 25 °C in a mixture of aqueous buffer (pH 8) and polar organic solvents such as ethanol, methanol, or acetonitrile. ...

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[Card,P.J.; Friedli,F.E.; Shechter,H. Journal of the American Chemical Society, 1983 , vol. 105, p. 6104]

Reductive cleavage of aryl oxazolines to benzaldehydes and s...

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Palladium-Catalyzed Cyclization of. omega.-Haloallenes. A Ne...

[Ma, Shengming; Negishi, Ei-Ichi Journal of the American Chemical Society, 1995 , vol. 117, # 23 p. 6345 - 6354]

No. 1-2902

[Brown, George R.; Foubister, Alan J. Synthesis, 1982 , # 12 p. 1036 - 1037]

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