Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical

S Hamada, Y Wada, T Sasamori, N Tokitoh, T Furura…

文献索引：Hamada, Shohei; Wada, Yoshiyuki; Sasamori, Takahiro; Tokitoh, Norihiro; Furura, Takumi; Kawabata, Takeo Tetrahedron Letters, 2014 , vol. 55, # 11 p. 1943 - 1945

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被引用次数: 2

摘要

Kinetic resolution of racemic alcohols is an alternative to asymmetric reduction of the corresponding ketones for obtaining optically active alcohols. An advantage of kinetic resolution is being able to produce optically active compounds with extremely high enantiomeric purity under the proper control of the reaction conversion. 1 Acylative kinetic resolution of racemic alcohols has been extensively developed. 2 Oxidative kinetic resolution of racemic alcohols has also been ...