Tetrahedron Letters

Synthesis of sterically hindered ketones from aldehydes via O-silyl oximes

JG Kim, MK Mishra, DO Jang

文献索引：Kim, Joong-Gon; Mishra, Mithilesh Kumar; Jang, Doo Ok Tetrahedron Letters, 2012 , vol. 53, # 27 p. 3527 - 3529

被引用次数: 1

摘要

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... A mild and efficient method to synthesize sterically hindered ketones from aldehydes via O-silyl oximes was developed. Treatment of O-triphenylsilylated oximes with alkyl iodides in the presence of triethyl borane afforded the corresponding ketones. ... As a part of our ongoing research, we ...

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2, 2, 4-三甲基-3-戊酮

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~72%

~10%

~9%

~73%

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~45%

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