Correlation of the rates of solvolysis of 4-morpholinecarbonyl chloride using the extended Grunwald-Winstein equation

R Kim, D Ali, JP Lee, KY Yang…

文献索引：Kim, Ran; Ali, Dildar; Lee, Jong Pal; Yang, Kiyull; Koo, In Sun Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 7 p. 1963 - 1967

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被引用次数: 5

摘要

Abstract The rates of solvolysis of 4-morpholinecarbonyl chloride (MPC) have measured at in water,,, and in aqueous binary mixtures of acetone, ethanol, methanol, and 2, 2, 2- trifluoroethanol. An extended (two-term) Grunwald-Winstein equation correlation gave sensitivities towards changes in solvent nucleophilicity and solvent ionizing power as expected for a dissociative and/or (ionization) pathway. For nine solvents specific rates ...