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Enol nitrosation revisited: Determining reactivity of ambident nucleophiles

…, JC Mejuto, M Parajó, M Pérez??Lorenzo

文献索引:Garcia-Rio, Luis; Mejuto, Juan C.; Parajo, Mercedes; Perez-Lorenzo, Moises European Journal of Organic Chemistry, 2009 , # 26 p. 4525 - 4533

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被引用次数: 7

摘要

Abstract Enols are one of the most important types of ambident nucleophiles being widely used as reagents in organic chemistry. The relevance of enols has led to considerable interest in developing methods to determine the reactivity of their nucleophilic centers. In this sense, the mainstream literature works on this topic make use of a combination of overall rate constants together with the analysis of the reaction products. By knowing the product ...