Enol nitrosation revisited: Determining reactivity of ambident nucleophiles

…, JC Mejuto, M Parajó, M Pérez??Lorenzo

Index: Garcia-Rio, Luis; Mejuto, Juan C.; Parajo, Mercedes; Perez-Lorenzo, Moises European Journal of Organic Chemistry, 2009 , # 26 p. 4525 - 4533

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Citation Number: 7

Abstract

Abstract Enols are one of the most important types of ambident nucleophiles being widely used as reagents in organic chemistry. The relevance of enols has led to considerable interest in developing methods to determine the reactivity of their nucleophilic centers. In this sense, the mainstream literature works on this topic make use of a combination of overall rate constants together with the analysis of the reaction products. By knowing the product ...