Highly efficient P–N nickel (II) complexes for the dimerisation of ethylene

…, A Auffrant, C Klemps, L Vu-Do, L Boubekeur…

文献索引：Buchard, Antoine; Auffrant, Audrey; Klemps, Christian; Vu-Do, Laurence; Boubekeur, Leila; Goff, Xavier F. Le; Floch, Pascal Le Chemical Communications, 2007 , # 15 p. 1502 - 1504

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被引用次数: 14

摘要

Short chain length α-olefins have found numerous applications for the preparation of commercially relevant compounds. 1 Particularly, they are used as comonomers in the synthesis of low-density polyethylene. Among processes that are able to furnish α-olefins (cracking of paraffins, dehydrogenation, dehydration, chain growth) the oligomerisation of ethylene is probably the most rewarding process since it can produce selectively C 4 , C 6 and C 8 α-olefins which ...