Chemical Communications 2008-04-07

Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)-CF(3) reagents.

Patrick Eisenberger, Iris Kieltsch, Nicolas Armanino, Antonio Togni

文献索引：Chem. Commun. (Camb.) 13 , 1575-1577, (2008)

摘要

A direct, mild and efficient trifluoromethylation of primary and secondary phosphines is achieved with easily accessible, cheap hypervalent iodine compounds acting as electrophilic CF(3)-transfer reagents.

结构式	名称/CAS号	分子式	全部文献
	3,3-二甲基-1-(三氟甲基)-1,2-苯并碘氧杂戊环 CAS:887144-97-0	C₁₀H₁₀F₃IO

A Ritter-type reaction: direct electrophilic trifluoromethyl...
2011-02-01
[Angew. Chem. Int. Ed. Engl. 5th ed., 50 , 1059-1063, (2011)]

The productive merger of iodonium salts and organocatalysis:...
2010-04-14
[J. Am. Chem. Soc. 132 , 4986-4987, (2010)]

Pd(II)-catalyzed ortho-trifluoromethylation of arenes using ...
2010-03-24
[J. Am. Chem. Soc. 11th ed., 132 , 3648-3649, (2010)]

Copper-catalyzed trifluoromethylation of aryl and vinyl boro...
2011-05-06
[Org. Lett. 13 , 2342-2345, (2011)]

Highly selective trifluoromethylation of 1,3-disubstituted a...
2012-01-09
[Angew. Chem. Int. Ed. Engl. 2nd ed., 51 , 540-543, (2012)]

Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)-CF(3) reagents.

摘要

相关化合物