Journal of the American Chemical Society 2010-03-24

Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter.

Xisheng Wang, Larry Truesdale, Jin-Quan Yu

文献索引：J. Am. Chem. Soc. 11th ed., 132 , 3648-3649, (2010)

摘要

A Pd(II)-catalyzed C-H activation/trifluoromethylation of arenes with an electrophilic trifluoromethylation reagent using diverse heterocycle directing groups is reported. The presence of trifluoroacetic acid is crucial for this catalytic reaction.

结构式	名称/CAS号	分子式	全部文献
	3,3-二甲基-1-(三氟甲基)-1,2-苯并碘氧杂戊环 CAS:887144-97-0	C₁₀H₁₀F₃IO
	5-(三氟甲基)二苯并噻吩四氟硼酸 CAS:131880-16-5	C₁₃H₈BF₇S

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Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter.

摘要

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