Journal of the American Chemical Society 2010-03-24

Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter.

Xisheng Wang, Larry Truesdale, Jin-Quan Yu

Index: J. Am. Chem. Soc. 11th ed., 132 , 3648-3649, (2010)

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Abstract

A Pd(II)-catalyzed C-H activation/trifluoromethylation of arenes with an electrophilic trifluoromethylation reagent using diverse heterocycle directing groups is reported. The presence of trifluoroacetic acid is crucial for this catalytic reaction.

Structure	Name/CAS No.	Molecular Formula	Articles
	Togni's Reagent CAS:887144-97-0	C₁₀H₁₀F₃IO
	S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate CAS:131880-16-5	C₁₃H₈BF₇S

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Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter.

Abstract

Related Compounds