Tetrahedron

The functionalization of saturated hydrocarbons. Part 24. The use of tert-butyl hydroperoxide: GoAgg IV and GoAgg V.

DHR Barton, W Chavasiri

文献索引：Barton, Derek H. R.; Chavasiri, Warinthorn Tetrahedron, 1994 , vol. 50, # 1 p. 19 - 30

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被引用次数: 49

摘要

The use of tert-butyl hydroperoxide as an oxidant in Gif-type systems (GoAggIV and GoAgfV) catalyzed by various Fe (III) species is examined. Regioselectivity studids of these systems have revealed several characteristics similar to those observed for other prdviously reported Gif-type reactions. A common rdaction pathway for the GoAggIV and GoAggV oxidation systems and other Gif-type reactions (from alkane via alkyl hydroperoxide to ketone or ...